CHARACTERIZATION, LUMINESCENT PROPERTIES, AND CRYSTAL STRUCTURE DETERMINATION OF [Pt(Ph2bipy)Cl2]

被引：6

作者：

Shamaei, S. ^{[1
]}

Heidari, A. ^{[2
]}

Amani, V. ^{[3
]}

机构：

[1] Islamic Azad Univ, Khoramabad Branch, Fac Sci, Dept Chem, Khorramabad, Iran

[2] Univ Zabol, Dept Chem, Zabol, Iran

[3] Farhangian Univ, Dept Chem, Shahid Beheshti Campus, Tehran, Iran

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 08期

关键词：

synthesis; crystal structure; platinum(II) complex; 4,4 '-diphenyl-2,2 '-bipyridine; luminescent properties; PT(II) CHLORIDE COMPLEXES; PLATINUM(II) COMPLEXES; LIGANDS; MONONUCLEAR; BIPYRIDINE; CHEMISTRY; CISPLATIN; PLANE; DRUG;

D O I：

10.1134/S0022476616080266

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New complex [Pt(Ph(2)bipy)Cl-2] (1) is obtained from the reaction of H2PtCl6 center dot 6H(2)O and 4,4'-diphenyl-2,2'-bipyridine (Ph(2)bipy) in a mixture of methanol, chloroform, and dimethyl sulfoxide. Suitable crystals of 1 for the diffraction experiment are obtained by slow evaporation of the resulted orange solution at room temperature. This complex is characterized by elemental analysis, IR, H-1 NMR, UV-Vis, and luminescence spectroscopy and its structure is studied by the single crystal X-ray diffraction method. X-ray structure determination shows that in the structure of this compound, the Pt(II) atom is four-coordinated in a distorted square-planar configuration by two nitrogen atoms from a bidentate 4,4'-diphenyl-2,2'-bipyridine ligand and two terminal chlorine atoms.

引用

页码：1675 / 1679

页数：5

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