Structure of the framework complex K0.4Cs0.6{Cd(H2O)2Re6S8(CN)4(OH)(H2O)}aEuro¢8H2O

被引：1
作者：
Ledneva, A. Yu. [1 ]
Virovets, A. V. [1 ,2 ]
Naumov, N. G. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 05期
关键词：
synthesis; rhenium; octahedral cluster; cadmium; topological crystal chemistry; hydrogen bond; RHENIUM CLUSTER COMPLEXES; CHALCOCYANIDE CLUSTER; CRYSTAL-STRUCTURES; ANIONS; SE;
D O I：
10.1134/S0022476615050327
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By single crystal X-ray diffraction, the structure of a new compound based on octahedral mixed-ligand anionic cluster complexes of rhenium and cadmium(II) cations is determined: K0.4Cs0.6{Cd(H2O)(2)Re6S8(CN)(4)(OH)(H2O)}aEuro8H(2)O (1). The compound has a framework structure with a pts (platinum sulfide) topology. The cluster anions are additionally chained together by strong OHa <-H2O hydrogen bonds between the terminal ligands of neighboring clusters; the Oa <-O distance is 2.464 angstrom .
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页码：1024 / 1027
页数：4
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