A facile fabrication of silver/copper oxide nanocomposite: An innovative entry in photocatalytic and biomedical materials

被引:58
作者
Khan, Afaq Ullah [1 ]
Khan, Arif Ullah [1 ,2 ]
Li, Baoshan [1 ]
Mahnashi, Mater H. [3 ]
Alyami, Bander A. [3 ]
Alqahtani, Yahya S. [3 ]
Tahir, Kamran [4 ]
Khan, Shafiullah [4 ]
Nazir, Sadia [4 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Beijing Adv Innovat Ctr Soft Matter Sci & Engn, Beijing 100029, Peoples R China
[3] Najran Univ, Coll Pharm, Dept Pharmaceut Chem, Najran, Saudi Arabia
[4] Gomal Univ, Inst Chem Sci, Dera Ismail Khan, KP, Pakistan
基金
中国国家自然科学基金;
关键词
Ag/CuO nanocomposite; Hydrothermal method; Photoinhibition of bacteria; Photocatalytic degradation of methyl orange; DPPH; SILVER NANOPARTICLES; GREEN SYNTHESIS; ESCHERICHIA-COLI; IN-VITRO; ANTIBACTERIAL; COPPER; ROUTE; CUO; INACTIVATION; DEGRADATION;
D O I
10.1016/j.pdpdt.2020.101814
中图分类号
R73 [肿瘤学];
学科分类号
100214 ;
摘要
In this work, principles and techniques of green chemistry were implemented which exploit environmentally and economically friendly methods using an accessible and non-toxic medium, that is water and ascorbic acid (Vit.C), which leads to the synthesis of silver/ copper oxide (Ag/CuO) nanocomposite. Vit.C was used to furnish the synthesis of excellent and controlled crystalline silver nanoparticles (AgNPs), copper oxide (CuO) and Ag/CuO nanocomposite. Moreover, the structures of all the synthesized nanomaterials were confirmed by wide range of characterization techniques which include UV-vis spectroscopy, FTIR, X-ray diffraction and Electron Diffraction Spectroscopy. However external and internal morphology of newly synthesized nanomaterials were examined by using Scanning Electron Microscopy and High resolution Transmission Electron Microscopy, respectively. The prepared nanomaterials were evaluated for catalytic decomposition of methyl orange (MO) in dark, visible light and UV light. The results showed that 20 %, 50 % and 90 % degradation of MO in 40 min was observed in dark, visible light and UV light, respectively. To further explore the biological potential of synthesized Ag/CuO nanocomposite, we also evaluated it for an inactivation of bacteria where Escherichia coli has 17( +/- 0.5 mm) and Staphylococcus aureus has 20 ( +/- 0.6 mm) zone of inhibition in light. The results showed that reactive oxygen species (ROS) were produced in the presence of light and Ag/CuO. These ROS are the main source of inactivation of bacteria. The prepared nanomaterial has also good efficiency against DPPH stabilization. Further study is required to investigate the hidden applications of the as synthesized nanomaterials.
引用
收藏
页数:9
相关论文
共 47 条
[1]   Silver and gold nanoparticles from Sargentodoxa cuneata: synthesis, characterization and antileishmanial activity [J].
Ahmad, Aftab ;
Syed, Fatima ;
Shah, Akram ;
Khan, Zahid ;
Tahir, Kamran ;
Khan, Arif Ullah ;
Yuan, Qipeng .
RSC ADVANCES, 2015, 5 (90) :73793-73806
[2]  
Ahmad W., 2019, APPL NANOSCI, P1
[3]   Simple synthesis of CuO/Ag nanocomposite electrode using precursor ink for non-enzymatic electrochemical hydrogen peroxide sensing [J].
Antink, Wytse Hooch ;
Choi, Yejung ;
Seong, Kwang-dong ;
Piao, Yuanzhe .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 255 :1995-2001
[4]   Characterisation and antifungal activity of silver nanoparticles biologically synthesised by Amaranthus retroflexus leaf extract [J].
Bahrami-Teimoori, Bahram ;
Nikparast, Yaser ;
Hojatianfar, Mostafa ;
Akhlaghi, Mahdi ;
Ghorbani, Reza ;
Pourianfar, Hamid Reza .
JOURNAL OF EXPERIMENTAL NANOSCIENCE, 2017, 12 (01) :129-139
[5]   Controlled synthesis of copper nano/microstructures using ascorbic acid in aqueous CTAB solution [J].
Bicer, Mustafa ;
Sisman, Ilkay .
POWDER TECHNOLOGY, 2010, 198 (02) :279-284
[6]   Biomedical Applications of Silver Nanoparticles: An Up-to-Date Overview [J].
Burdusel, Alexandra-Cristina ;
Gherasim, Oana ;
Grumezescu, Alexandru Mihai ;
Mogoanta, Laurentiu ;
Ficai, Anton ;
Andronescu, Ecaterina .
NANOMATERIALS, 2018, 8 (09)
[7]   Silver nanoparticles in polymeric matrices for fresh food packaging [J].
Carbone, Marilena ;
Donia, Domenica Tommasa ;
Sabbatella, Gianfranco ;
Antiochia, Riccarda .
JOURNAL OF KING SAUD UNIVERSITY SCIENCE, 2016, 28 (04) :273-279
[8]   Convenient and Template-Free Route to One-Pot Green Synthesis of Polyrhodanine Core-Shell Nanoparticles [J].
Chauhan, Moni ;
Gaba, Anjali ;
Hong, Tao ;
Esperance, Evens ;
Johnson, Qiaxian ;
Longia, Gurjeet ;
Chauhan, Bhanu P. S. .
ACS OMEGA, 2018, 3 (09) :10974-10979
[9]   The inhibitory effects of silver nanoparticles, silver ions, and silver chloride colloids on microbial growth [J].
Choi, Okkyoung ;
Deng, Kathy Kanjun ;
Kim, Nam-Jung ;
Ross, Louis, Jr. ;
Surampalli, Rao Y. ;
Hu, Zhiqiang .
WATER RESEARCH, 2008, 42 (12) :3066-3074
[10]   A study on the in vitro percutaneous absorption of silver nanoparticles in combination with aluminum chloride, methyl paraben or di-n-butyl phthalate [J].
Domeradzka-Gajda, Katarzyna ;
Nocun, Marek ;
Roszak, Joanna ;
Janasik, Beata ;
Quarles, C. Derrick, Jr. ;
Wasowicz, Wojciech ;
Grobelny, Jaroslaw ;
Tomaszewska, Emilia ;
Celichowski, Grzegorz ;
Ranoszek-Soliwoda, Katarzyna ;
Cieslak, Malgorzata ;
Puchowicz, Dorota ;
Gonzalez, Jhanis J. ;
Russo, Richard E. ;
Stepnik, Maciej .
TOXICOLOGY LETTERS, 2017, 272 :38-48