Photocatalytic reduction of acetylpyridine to pinacol using [fac-Re(bpy)(CO)3{4-(MeCO)py}]+ (bpy = 2,2′-bipyridine, py = pyridine)

被引：4
作者：
Hori, H
Koike, K
Takeuchi, K
Ishitani, O
机构：
[1] Natl Inst Resources & Environm, Tsukuba, Ibaraki 3058569, Japan
[2] Saitama Univ, Grad Sch Sci & Engn, Urawa, Saitama 3388570, Japan
来源：
CHEMISTRY LETTERS | 2000年 / 04期
关键词：
D O I：
10.1246/cl.2000.376
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[fac-Re(bpy)(CO)(3){4(MeCO)py}](+) can act as an efficient photocatalyst for the reduction of 4-acetylpyridine to a pinacol (py-CMeOHCMeOH-py) in the presence of triethanolamine. The reaction proceeds via formation of a pinacol complex [fac-Re(bpy)(Co)(3)(py-CMeOHCMeOH-py)](+).
引用
收藏
页码：376 / 377
页数：2
相关论文
共 12 条
  • [1] PHOTOCHEMICAL AND ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE TO CARBON-MONOXIDE MEDIATED BY (2,2'-BIPYRIDINE)TRICARBONYLCHLORORHENIUM(I) AND RELATED COMPLEXES AS HOMOGENEOUS CATALYSTS
    HAWECKER, J
    LEHN, JM
    ZIESSEL, R
    [J]. HELVETICA CHIMICA ACTA, 1986, 69 (08) : 1990 - 2012
  • [2] Photoinduced formation of [fac-Re(bpy)(CO)3CN] from [fac-Re(bpy)(CO)3(4-CNpy)]+ (bpy=2,2′-bipyridine, py=pyridine):: CN group rearrangement of a cyanopyridine ligand onto central metal
    Hori, H
    Ishihara, J
    Koike, K
    Takeuchi, K
    Ibusuki, T
    Ishitani, O
    [J]. CHEMISTRY LETTERS, 1997, (12) : 1249 - 1250
  • [3] Photochemistry of [Re(bipy)(CO)(3)(PPh(3))](+) (bipy equals 2,2'-bipyridine) in the presence of triethanolamine associated with photoreductive fixation of carbon dioxide: Participation of a chain reaction mechanism
    Hori, H
    Johnson, FPA
    Koike, K
    Takeuchi, K
    Ibusuki, T
    Ishitani, O
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (06): : 1019 - 1023
  • [4] Photocatalytic reduction of carbon dioxide using [fac-Re(bpy)(CO)3(4-Xpy)]+ (Xpy = pyridine derivatives)
    Hori, H
    Ishihara, J
    Koike, K
    Takeuchi, K
    Ibusuki, T
    Ishitani, O
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1999, 120 (02) : 119 - 124
  • [5] Efficient photocatalytic CO2 reduction using [Re(bpy)(CO)(3){P(OEt)(3)}](+)
    Hori, H
    Johnson, FPA
    Koike, K
    Ishitani, O
    Ibusuki, T
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1996, 96 (1-3) : 171 - 174
  • [6] Electrospray mass spectrometric detection of neutral metal bipyridine complexes using sodium ions and its application in the analysis of a photochemical ligand substitution reaction
    Hori, H
    Ishihara, J
    Koike, K
    Takeuchi, K
    Ibusuki, T
    Tanabe, J
    Ishitani, O
    [J]. ANALYTICAL SCIENCES, 1998, 14 (02) : 287 - 292
  • [7] REDOX-PHOTOSENSITIZED REACTIONS .13. RU(BPY)3(2+)-PHOTOSENSITIZED REACTIONS OF AN NADH MODEL, 1-BENZYL-1,4-DIHYDRONICOTINAMIDE, WITH AROMATIC CARBONYL-COMPOUNDS AND COMPARISON WITH THERMAL-REACTIONS
    ISHITANI, O
    YANAGIDA, S
    TAKAMUKU, S
    PAC, C
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (13) : 2790 - 2796
  • [8] A NEW PATHWAY FOR PHOTOBLEACHING OF [FAC-RE(2,2'-BIPYRIDINE)(CO)3BR] BY TRIETHYLAMINE - ETHYLATION OF THE BIPYRIDINE LIGAND
    ISHITANI, O
    NAMURA, I
    YANAGIDA, S
    PAC, C
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (15) : 1153 - 1154
  • [9] Kalyanasundaram K., 1992, Photochemistry of Polypyridine and Porphyrin Complexes
  • [10] Key process of the photocatalytic reduction of CO2 using [Re(4,4′-X2-bipyridine)(CO)3PR3]+ (X = CH3, H, CF3;: PR3 = phosphorus ligands):: Dark reaction of the one-electron-reduced complexes with CO2
    Koike, K
    Hori, H
    Ishizuka, M
    Westwell, JR
    Takeuchi, K
    Ibusuki, T
    Enjouji, K
    Konno, H
    Sakamoto, K
    Ishitani, O
    [J]. ORGANOMETALLICS, 1997, 16 (26) : 5724 - 5729
12