Recent Advances in Nonprecious Metal Oxide Electrocatalysts and Photocatalysts for N2 Reduction Reaction under Ambient Condition

被引：74

作者：

Xu, Tong ^{[1
,2
]}

Liang, Jie ^{[1
]}

Li, Shaoxiong ^{[1
]}

Xu, Zhaoquan ^{[1
]}

Yue, Luchao ^{[1
]}

Li, Tingshuai ^{[1
]}

Luo, Yonglan ^{[1
]}

Liu, Qian ^{[1
]}

Shi, Xifeng ^{[3
]}

Asiri, Abdullah M. ^{[4
,5
]}

Yang, Chun ^{[2
]}

Sun, Xuping ^{[1
]}

机构：

[1] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Sichuan, Peoples R China

[2] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610068, Sichuan, Peoples R China

[3] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China

[4] King Abdulaziz Univ, Dept Chem, Fac Sci, POB 80203, Jeddah 21589, Saudi Arabia

[5] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, POB 80203, Jeddah 21589, Saudi Arabia

来源：

SMALL SCIENCE | 2021年 / 1卷 / 05期

基金：

中国国家自然科学基金;

关键词：

ambient conditions; electrocatalysis; N-2 reduction reaction; nonprecious metal oxides; photocatalysis; SURFACE OXYGEN VACANCIES; NITROGEN REDUCTION; AMMONIA-SYNTHESIS; DOPED TIO2; PHOTOCHEMICAL-SYNTHESIS; EVOLUTION REACTION; HYDROGEN STORAGE; QUANTUM DOTS; IN-SITU; EFFICIENT;

D O I：

10.1002/smsc.202000069

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

NH3 plays an indispensable role in agriculture, fertilizer production as well as in the chemical industry. However, its large-scale production still relies deeply on the century-old Haber-Bosch process under high temperature and pressure along with greenhouse gas emission and fossil fuel consumption. The electrocatalytic and photocatalytic N-2 reduction reactions (NRRs) for NH3 production are favorable approaches to avoid these issues because they are carbon-neutral and energy-saving. Recently, the nonprecious metal oxides (NPMO) have gathered the most attention due to their ease of synthesis, controllable stability, lower cost, and environmental friendliness. Herein, the recent advances in NPMO electrocatalysts and photocatalysts for the NRR are narrated and the strategies to improve the poor NRR activity of pristine NPMOs by heteroatom doping to engineer their surface-active sites and introduction of oxygen vacancies are highlighted. A brief summary of and the future perspective on this research field are also presented.

引用

页数：18

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