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Lanthanide-Based Luminescent Hybrid Materials
被引:3058
作者:
Binnemans, Koen
[1
]
机构:
[1] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium
关键词:
RARE-EARTH-METAL;
SOL-GEL SILICA;
INTRAMOLECULAR ENERGY-TRANSFER;
ORGANIC ELECTROLUMINESCENT DEVICES;
NEAR-INFRARED-LUMINESCENCE;
SURFACTANT-ENCAPSULATED POLYOXOMETALATE;
LANGMUIR-BLODGETT-FILMS;
IN-SITU SYNTHESIS;
LAYERED DOUBLE HYDROXIDES;
MOLECULAR-BASED HYBRIDS;
D O I:
10.1021/cr8003983
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The different types of lanthanide based hybrid materials and their advantages and disadvantages have been demonstrated. These hybrid materials have superior mechanical properties and have a better processability than the pure molecular lanthanide complexes and embedding a lanthanide complex in a hybrid matrix is also beneficial for its thermal stability and luminescence output. The first lanthanide doped sol-gel silica glasses samples were prepared by dissolving inorganic lanthanide salts like hydrated europium, chloride or europium nitrate in the solution. The incorporation of a lanthanide complex into an inorganic hybrid matrix significantly improves its thermal and (photo) chemical stability. The lanthanide-doped nanoparticle offers an alternative for the lanthanide β-dike-tonates.
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页码:4283 / 4374
页数:92
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