Preliminary Surrogate Mixture Models for the Thermophysical Properties of Rocket Propellants RP-1 and RP-2

被引:102
作者
Huber, M. L. [1 ]
Lemmon, E. W. [1 ]
Ott, L. S. [1 ]
Bruno, T. J. [1 ]
机构
[1] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA
关键词
THERMAL-DECOMPOSITION KINETICS; DISTILLATION CURVES; AVIATION FUEL; JET; REFRIGERANTS; CONDUCTIVITY; IMPROVEMENTS; VISCOSITY; JP-8; FORMULATION;
D O I
10.1021/ef900216z
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
We have developed surrogate mixture models to represent the thermophysical properties of two kerosene rocket propellants, RP-I and RP-2. The surrogates were developed with a procedure that incorporated experimental data for the density, sound speed, viscosity, thermal conductivity, and the advanced distillation curves for samples of the two fuels. The surrogate for RP-I contains four components (alpha-methyldecalin, n-dodecane, 5-methylnonane, and heptylcyclohexane), and the surrogate for RP-2 contains five components (alpha-methyldecatin, n-dodecane, 5-methylnonane, 2,4-dimethyinonane, and heptylcyclohexane). Comparisons with experimental data demonstrate that the models are able to represent the density, sound speed, viscosity, and thermal conductivity of both fuels to within (at a 95% confidence level) 0.4, 2, 2, and 4%, respectively. The volatility behavior, as measured by the advanced distillation curves, is reproduced to within 0.5%.
引用
收藏
页码:3083 / 3088
页数:6
相关论文
共 61 条
[1]   Thermal decomposition kinetics of RP-1 rocket propellant [J].
Andersen, PC ;
Bruno, TJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (06) :1670-1676
[2]   Rapid screening of fluids for chemical stability in organic rankine cycle applications [J].
Andersen, WC ;
Bruno, TJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (15) :5560-5566
[3]  
[Anonymous], MILDTL25576E
[4]  
[Anonymous], 2007, 6646 NISTIR
[5]  
[Anonymous], 2001, J AM CHEM SOC, DOI DOI 10.1021/JA0048634
[6]   Enthalpy of combustion of fuels as a function of distillate cut: Application of an advanced distillation curve method [J].
Bruno, Thomas J. ;
Smith, Beverly L. .
ENERGY & FUELS, 2006, 20 (05) :2109-2116
[7]   Improvements in the measurement of distillation curves. 1. A composition-explicit approach [J].
Bruno, TJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (12) :4371-4380
[8]   Improvements in the measurement of distillation curves. 2. Application to aerospace/aviation fuels RP-1 and s-8 [J].
Bruno, TJ ;
Smith, BL .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (12) :4381-4388
[9]   Method and apparatus for precision in-line sampling of distillate [J].
Bruno, TJ .
SEPARATION SCIENCE AND TECHNOLOGY, 2006, 41 (02) :309-314
[10]   Conditioning of flowing multiphase samples for chemical analysis [J].
Bruno, TJ .
SEPARATION SCIENCE AND TECHNOLOGY, 2005, 40 (08) :1721-1732