Preliminary Surrogate Mixture Models for the Thermophysical Properties of Rocket Propellants RP-1 and RP-2

被引:99
|
作者
Huber, M. L. [1 ]
Lemmon, E. W. [1 ]
Ott, L. S. [1 ]
Bruno, T. J. [1 ]
机构
[1] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO 80305 USA
关键词
THERMAL-DECOMPOSITION KINETICS; DISTILLATION CURVES; AVIATION FUEL; JET; REFRIGERANTS; CONDUCTIVITY; IMPROVEMENTS; VISCOSITY; JP-8; FORMULATION;
D O I
10.1021/ef900216z
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
We have developed surrogate mixture models to represent the thermophysical properties of two kerosene rocket propellants, RP-I and RP-2. The surrogates were developed with a procedure that incorporated experimental data for the density, sound speed, viscosity, thermal conductivity, and the advanced distillation curves for samples of the two fuels. The surrogate for RP-I contains four components (alpha-methyldecalin, n-dodecane, 5-methylnonane, and heptylcyclohexane), and the surrogate for RP-2 contains five components (alpha-methyldecatin, n-dodecane, 5-methylnonane, 2,4-dimethyinonane, and heptylcyclohexane). Comparisons with experimental data demonstrate that the models are able to represent the density, sound speed, viscosity, and thermal conductivity of both fuels to within (at a 95% confidence level) 0.4, 2, 2, and 4%, respectively. The volatility behavior, as measured by the advanced distillation curves, is reproduced to within 0.5%.
引用
收藏
页码:3083 / 3088
页数:6
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