Copper-Catalyzed Oxidative -Alkylation of -Amino Carbonyl Compounds with Ethers via Dual C(sp3)-H Oxidative Cross- Coupling

被引：121
作者：
Wei, Wen-Ting [1 ]
Song, Ren-Jie [1 ]
Li, Jin-Heng [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 08期
关键词：
alkylation; -amino carbonyl compounds; tert-butyl hydrogen peroxide (TBHP); copper; C(sp3)H functionalization; ethers; C-H BONDS; NATURAL-PRODUCTS; PHOTOINDUCED FORMATION; ASYMMETRIC-SYNTHESIS; DIRECT ARYLATION; ALPHA-ARYLATION; DERIVATIVES; VINYL; ALKENYLATION; CHEMISTRY;
D O I：
10.1002/adsc.201301091
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A novel copper-catalyzed oxidative alkylation of -amino carbonyl compounds with ethers has been established for the selective synthesis of -etherized -amino carbonyl compounds. This oxidative alkylation is achieved by dual C(sp3)H bond oxidative cross-coupling, and its scope is expanded to -amino ketones, -amino esters and -amino amides.
引用
收藏
页码：1703 / 1707
页数：5
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