Ni-Pd bimetallic catalysts for the direct synthesis of H2O2 - unusual enhancement of Pd activity in the presence of Ni

被引：78

作者：

Maity, S. ^{[1
]}

Eswaramoorthy, M. ^{[1
]}

机构：

[1] Jawaharlal Nehru Ctr Adv Sci Res, Nanomat & Catalysis lab, Chem & Phys Mat Unit, Jakkur PO, Bangalore 560064, Karnataka, India

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2016年 / 4卷 / 09期

关键词：

HYDROGEN-PEROXIDE SYNTHESIS; GOLD-PALLADIUM CATALYSTS; H-2; O-2; NANOPARTICLES; AU; OXYGEN; OXIDATION; METHANOL;

D O I：

10.1039/c6ta00486e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Direct synthesis of hydrogen peroxide from molecular H-2 and O-2 is one of the challenging reactions for several decades in terms of catalyst selection, stability and selectivity. Herein, we report a bimetallic NiPd nanocatalyst showing unusually high, three times higher activity compared to Pd nanocatalysts. The catalyst also shows very long life time, 72 h, with high activity under harsh acidic conditions.

引用

页码：3233 / 3237

页数：5

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