Research Advance on Enantioselective Transition Metal-Catalyzed Hydroacylation Reactions

被引：5
作者：
Wang Haorui
Ye Mengchun [1 ]
机构：
[1] Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 42卷 / 10期
基金：
中国国家自然科学基金;
关键词：
transition metal catalysis; hydroacylation; asymmetric catalysis; aldehydes; alkenes; ASYMMETRIC CYCLIZATION REACTIONS; INTERMOLECULAR HYDROACYLATION; INTRAMOLECULAR HYDROACYLATION; POLYCYCLIC NITROGEN; KINETIC RESOLUTION; RHODIUM; ALKENE; DESYMMETRIZATION; 4-PENTENALS; ALDEHYDES;
D O I：
10.6023/cjoc202207036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition metal-catalyzed hydroacylation reaction of aldehydes with p-unsaturated compounds provides an economical and efficient method for the construction of C-C bonds, not only allowing readily available starting materials to be used as substrates, but also featuring high atom and step economy. Therefore, the reaction has received continuous and extensive attention during the past several decades. The advances on enantioselective transition metal-catalyzed hydroacylation reactions are summarized, focusing on reaction types, asymmetric strategies and reaction mechanisms.
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收藏
页码：3152 / 3166
页数：15
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