Nanoscale silicon as anode for Li-ion batteries: The fundamentals, promises, and challenges

被引：268

作者：

Gu, Meng ^{[1
]}

He, Yang ^{[2
]}

Zheng, Jianming ^{[3
]}

Wang, Chongmin ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA

[2] Univ Pittsburgh, Dept Mech Engn & Mat Sci, Pittsburgh, PA 15261 USA

[3] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA

来源：

NANO ENERGY | 2015年 / 17卷

关键词：

Lithium ion battery; Si anode; Capacity fading; Nanoscale design; High capacity; Long cycle life; in-situ TEM; IN-SITU TEM; ELECTROCHEMICAL LITHIATION; LITHIUM; NANOWIRES; NANOPARTICLES; FRACTURE; DESIGN; NANOPILLARS; ELECTRODES; KINETICS;

D O I：

10.1016/j.nanoen.2015.08.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silicon (Si), associated with its natural abundance, low discharge voltage vs. Li/Li+, and extremely high theoretical capacity (similar to 4200 mAh g(-1),), has been extensively explored as anode for lithium ion battery. One of the key challenges for using Si as anode is the large volume change upon lithiation and delithiation, which causes a fast capacity fading. Over the last few years, dramatic progress has been made for addressing this issue. In this paper, we review the progress towards tailoring of Si as anode for lithium ion battery. The paper is organized such that it covers the fundamentals, the promises offered by nanoscale designs, and the challenges that remained to be addressed to allow the application of Si based materials as high capacity anode for lithium ion batteries. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：366 / 383

页数：18

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