Ground-State Properties of Two-Dimensional Symmetrical Mixtures in an External Field of Square Symmetry

被引：4
作者：
Salamacha, L. [1 ]
Patrykiejew, A. [1 ]
Sokolowski, S. [1 ]
机构：
[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Modelling Physicochem Proc, PL-20031 Lublin, Poland
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 42期
关键词：
PHASE-DIAGRAMS; MEAN-FIELD; BINARY-MIXTURES; CRITICAL-BEHAVIOR; ADSORBED LAYERS; TRANSITIONS; EQUILIBRIA; MODEL; ADSORPTION; SIMULATION;
D O I：
10.1021/jp901383v
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The ground-state behavior of two-dimensional symmetrical mixtures subjected to the external potential of square symmetry is discusses. It is demonstrated that different commensurate, high order commensurate as well as incommensurate phases may appear depending on the properties of the mixture as well as on the corrugation of external potential. In particular, it is shown that a finite corrugation of external potential considerably influences the stability of-different ordered states. The ground-state calculations are confirmed by finite temperature grand canonical Monte Carlo simulations.
引用
收藏
页码：13687 / 13696
页数：10
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