On the Role of Metal Contaminants in Catalyses with FeCl3

被引：452
作者：
Buchwald, Stephen L. [1 ]
Bolm, Carsten [2 ]
机构：
[1] MIT, Cambridge, MA 02139 USA
[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 31期
关键词：
arylation; copper; homogeneous catalysis; iron trichloride; metal impurities; IRON/COPPER COCATALYZED ALKYNYLATION; CROSS-COUPLING REACTIONS; ARYL IODIDES; NITROGEN NUCLEOPHILES; C-N; ARYLATION REACTIONS; TERMINAL ALKYNES; BOND FORMATION; ZINC METAL; COPPER;
D O I：
10.1002/anie.200902237
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Warning: Catalyzed N-, O-, and C-arylation reactions ascribed to FeCl 3 can instead result from catalysis by trace quantities of copper salts. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5586 / 5587
页数：2
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