Reaction of gold(III) oxo complexes with alkenes.: Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6].: Crystal structure of [Au(bipyip)(η2-CH2=CHPh)][PF6] (bipyip=6-isopropyl-2,2′-bipyridine)

被引：50

作者：

Cinellu, MA

Minghetti, G

Stoccoro, S

Zucca, A

Manassero, M

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[2] Univ Milan, Ctr CNR, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 14期

关键词：

D O I：

10.1039/b404890c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gold alkene complexes [Au(bipy(R))(eta(2)-alkene)][PF6] (bipy(R)=6-alkyl-2,2'-bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au-2(bipy(R))(2)(mu-O)(2)][PF6](2) with alkenes. The crystal structure of the styrene adduct [Au(bipy(ip))(eta(2)-CH2=CHPh)][PF6] (bipy(ip)=6-isopropyl-2,2'-bipyridine) has been solved by X-ray analysis.

引用

页码：1618 / 1619

页数：2

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