Cationic [(Iminophosphine) Nickel( Allyl)]+ Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes

被引：25
作者：
Tafazolian, Hosein [1 ]
Schmidt, Joseph A. R. [1 ]
机构：
[1] Univ Toledo, Dept Chem & Biochem, Sch Green Chem & Engn, Coll Nat Sci & Math, 2801 W Bancroft St MS 602, Toledo, OH 43606 USA
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 07期
基金：
美国国家科学基金会;
关键词：
INTERMOLECULAR HYDROAMINATION; REGIOSELECTIVE HYDROAMINATION; ASYMMETRIC HYDROAMINATION; ACTIVATED OLEFINS; SECONDARY-AMINES; ALKYNES; REAGENTS; ALKENES; 1,3-DIENES; AMINATION;
D O I：
10.1002/chem.201605611
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of nickel-catalyzed hydroamination of allenes is reported. The new cationic [( 3-iminophosphine) nickel( allyl)](+)catalysts have been fully characterized and act regioselectively in the catalytic hydroamination of allenes with secondary amines at room temperature.
引用
收藏
页码：1507 / 1511
页数：5
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