Synthesis and Crystal Structure of [2-Hydroxy-5-(4-hydroxy-3-phenyliminomethyl-benzyl)-benzylidene]-phenyl-amine

被引:0
作者
Ding Yu [1 ]
Ku Zong-Jun [1 ]
Zhou Huan-Bo [1 ]
Yu Hua-Li [1 ]
Gao Da-Shun [1 ]
机构
[1] Xiaogan Univ, Sch Chem & Mat Sci, Xiaogan 432000, Peoples R China
关键词
synthesis; crystal structure; 2-hydroxy-5-(4-hydroxy-3-phenyliminomethyl-benzyl)-benzylidene]-phenyl-amine; SCHIFF-BASE; BUILDING-BLOCKS; COMPLEXES; LIGAND;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The tide compound [2-hydroxy-5-(4-hydroxy-3-phenyliminomethyl-benzyl)-benzylidene]-phenyl-amine (C27H22N2O2, M-r = 406.47) was synthesized by 5,5'-methylene-bissalicylaldehyde with aminobenezene, and its crystal structure was determined by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group C2/c with a = 4.4026(6), b = 1.501(13), c = 0.95818(12) nm, beta = 90.868(2)degrees, V = 4.2813(9) nm(3), Z = 8, D-c = 1.292 g/cm(3), mu = 0.010, F(000) = 1744, R = 0.0576 and wR = 0.1450 for 3766 observed reflections with I > 2 sigma(I). X-ray analysis reveals that the molecule has a pair of intramolecular O-H center dot center dot center dot N hydrogen bonds.
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页码:699 / 702
页数:4
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