Total degradation of fenitrothion and other organophosphorus pesticides by catalytic oxidation employing Fe-TAML peroxide activators

被引：108

作者：

Chanda, Arani ^{[1
]}

Khetan, Sushil K. ^{[1
]}

Banerjee, Deboshri ^{[1
]}

Ghosh, Anindya ^{[1
]}

Collins, Terrence J. ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 37期

关键词：

D O I：

10.1021/ja064017e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Fe-TAML/H2O2 catalytic oxidation process achieves facile in-solution total degradation of fenitrothion and two other organophosphorus (OP) pesticides. Degradation products have been identified and quantified providing evidence for oxidative hydrolysis, oxidative desulfuration, perhydrolysis, and deep oxidation. Degradation pathways can be selected by pH control to completely obviate all toxic residuals. Aquatic toxicity assays support the environmental compatibility of the degradation process. Copyright © 2006 American Chemical Society.

引用

页码：12058 / 12059

页数：2

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