Synthesis and crystal structure of a new one-dimensional chain bioxygen-bridged complex {[Pb2(C8H7O3)2(H2O)2](ClO4)2}n

被引：1
作者：
Chen, Hu
Xu, Xing-You
Gao, Jian
Yang, Xu-Jie
Lu, Lu-De [1 ]
Wang, Xin
机构：
[1] Nanjing Univ Sci & Technol, Mat Chem Lab, Nanjing 210094, Peoples R China
[2] HuaiHai Inst Technol, Dept Chem Engn, Lianyungang, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2006年 / 36卷 / 05期
基金：
中国国家自然科学基金;
关键词：
crystal structure; synthesis; bridged; one-dimensional chain;
D O I：
10.1080/15533170600729029
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new one-dimensional chain binuclear lead(II) complex has been synthesized with bioxygen-bridged two lead(II) ion together with 3-methoxyl-4-hydroxyl-phenyaldehyde (vanillin). The crystal structure of the complex was determined by the X-ray diffraction. The complex crystalizes in triclinic system, space group P-1 with a =7.312(5)angstrom, b =9.047(6)angstrom, c =9.063(7)angstrom, alpha=98.484(12)degrees, beta=92.916(11)degrees, gamma=98.600(11)degrees, 584.7(7)angstrom(3) , F (000)=440, Z = 1, D-c = 2.702 g/cm(3) , R-1 = 0.0399, wR(2) = 0.1071. The coordination number of the lead is five. The coordination geometry of the Pb2+ ion is a irregularity polyhedron.
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页码：385 / 389
页数：5
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