Cycloaddition of Carbon Dioxide and Epoxides using Pentaerythritol and Halides as Dual Catalyst System

被引：168

作者：

Wilhelm, Michael E. ^{[1
]}

Anthofer, Michael H. ^{[1
]}

Cokoja, Mirza ^{[1
]}

Markovits, Iulius I. E. ^{[1
]}

Herrmann, Wolfgang A. ^{[1
]}

Kuehn, Fritz E. ^{[1
]}

机构：

[1] Tech Univ Munich, Catalysis Res Ctr, Chair Inorgan Chem Mol Catalysis, D-85747 Garching, Germany

来源：

CHEMSUSCHEM | 2014年 / 7卷 / 05期

关键词：

carbon dioxide fixation; cooperative effects; cycloaddition; green chemistry; organocatalysis; FORM CYCLIC CARBONATES; CHEMICAL FIXATION; IONIC LIQUIDS; PROPYLENE-OXIDE; CO2; VALORIZATION; MECHANISM; LIGNIN; KI;

D O I：

10.1002/cssc.201301273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of pentaerythritol with nucleophilic halide salts such as nBu(4)NI is used as a dual catalyst system for the cycloaddition of carbon dioxide (CO2) with a broad range of organic epoxides yielding the respective cyclic carbonates. Due to synergistic effects of the organocatalysts, excellent yields and selectivities could be achieved under mild reaction conditions. Moreover, the nontoxic, cost-efficient, and readily available system is easily recyclable without significant loss of reactivity, representing an exceptional sustainable approach for the fixation of CO2.

引用

页码：1357 / 1360

页数：4

共 50 条

[21] Copolymerization of lactide, epoxides and carbon dioxide: a highly efficient heterogeneous ternary catalyst system
Li, Xiang
Duan, Ran-long
Hu, Chen-yang
Pang, Xuan
Deng, Ming-xiao
POLYMER CHEMISTRY, 2021, 12 (11) : 1700 - 1706
[22] Titanium Incorporated Mesoporous Silica Immobilized Functional Ionic Liquid as an Efficient Reusable Catalyst for Cycloaddition of Carbon Dioxide to Epoxides
Hu, Yu Lin
Wang, Hong Bo
Chen, Zhi Wei
Li, Xiao Guang
CHEMISTRYSELECT, 2018, 3 (18): : 5087 - 5091
[23] Oxalamide-derived ionic polymer/carbon nanotube composites: Highly active heterogeneous catalyst for promoting cycloaddition of carbon dioxide to epoxides
Zha, Wenye
Chen, Ying
Wang, Hu
Chen, Weifeng
Lei, Yi-Zhu
Wan, Ya-Li
Zhong, Shenglai
JOURNAL OF CO2 UTILIZATION, 2025, 92
[24] Cross-linked polymer grafted with functionalized ionic liquid as reusable and efficient catalyst for the cycloaddition of carbon dioxide to epoxides
Dai, Wei-Li
Jin, Bi
Luo, Sheng-Lian
Yin, Shuang-Feng
Luo, Xu-Biao
Au, Chak-Tong
JOURNAL OF CO2 UTILIZATION, 2013, 3-4 : 7 - 13
[25] Solvent- and Co-Catalyst-Free Cycloaddition of Carbon Dioxide and Epoxides Catalyzed by Recyclable Bifunctional Niobium Complexes
Wen, Qin
Yuan, Xuexin
Zhou, Qiqi
Yang, Hai-Jian
Jiang, Qingqing
Hu, Juncheng
Guo, Cun-Yue
MATERIALS, 2023, 16 (09)
[26] Nitrogen-rich covalent-organic-framework as a recyclable heterogenous catalyst for the efficient cycloaddition of carbon dioxide with epoxides
Tariq, Waseem
Pudukudy, Manoj
Liu, Yi
Li, Shuangjiang
Zhang, Churu
Haider, Asif Ali
Lin, Li
Murtaza, Ghulam
Tahir, Muhammad Nauman
Zhi, Yunfei
Shan, Shaoyun
SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 353
[27] Functionalized β-Cyclodextrins Catalyzed Environment-Friendly Cycloaddition of Carbon Dioxide and Epoxides
Wen, Qin
Yuan, Xuexin
Zhou, Qiqi
Yang, Hai-Jian
Jiang, Qingqing
Hu, Juncheng
Guo, Cun-Yue
MATERIALS, 2023, 16 (01)
[28] Effect of the structure of alkylammonium halides on the outcome of carbon dioxide cycloaddition to oxiranes
I. S. Gabov
M. A. Ezhikova
M. I. Kodess
A. V. Pestov
Russian Chemical Bulletin, 2023, 72 : 2809 - 2814
[29] Carbon Dioxide Cycloaddition to Epoxides Promoted by Nicotinamidium Halide Catalysts: A DFT Investigation
Butera, Valeria
CHEMPLUSCHEM, 2023, 88 (07):
[30] Effect of the structure of alkylammonium halides on the outcome of carbon dioxide cycloaddition to oxiranes
Gabov, I. S.
Ezhikova, M. A.
Kodess, M. I.
Pestov, A. V.
RUSSIAN CHEMICAL BULLETIN, 2023, 72 (12) : 2809 - 2814

← 1 2 3 4 5 →