Luminescent properties of yttrium diphenylphosphinate activated by europium

被引：5
作者：
Francisco, Cristina S. [1 ]
Stucchi, Elizabeth B. [1 ]
de Abreu, Edson M. [1 ]
机构：
[1] UNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2006年 / 418卷 / 1-2期
基金：
巴西圣保罗研究基金会;
关键词：
yttrium diphenylphosphinate; luminescence spectroscopy; europium; quantum yield;
D O I：
10.1016/j.jallcom.2005.10.067
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The synthesis and spectroscopic characterization of yttrium diphenylphosphinates doped with europium are reported. The purity of all samples was confirmed by carbon and hydrogen micro analysis, thermal analysis, IR vibrational spectroscopy, and X-ray diffraction. Luminescence spectra indicated the presence of two or more symmetry centers. The dynamic luminescence measurements suggested that one symmetry site presented an inversion center, while the others had lower symmetry. The average quantum yield of Eu3+ emission in the yttrium, matrices was 60%. (c) 2005 Elsevier B.V. All rights reserved.
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页码：234 / 237
页数：4
相关论文
共 12 条
  • [1] ABREU EM, 2002, P REUN AN SOC BRAS Q, V25
  • [2] QUANTUM EFFICIENCY STANDARD FOR ULTRAVIOLET AND VISIBLE EXCITATION
    BRIL, A
    JAGERVEENIS, AWD
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (03) : 396 - 398
  • [3] Eu(III) and Gd(III) complexes with pirazyne-2-carboxylic acid:: luminescence and modelling of the structure and energy transfer process
    de Mesquita, ME
    Silva, FRGE
    Albuquerque, RQ
    Freire, RO
    da Conceiçao, EC
    da Silva, JEC
    Júnior, NBC
    de Sá, GF
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 366 (1-2) : 124 - 131
  • [4] DUSTAN PO, 1975, AN ACAD BRAS CIENC, V47, P97
  • [5] ELECTRONIC-TRANSITIONS OF ARYL PHOSPHINES
    FIFE, DJ
    MORSE, KW
    MOORE, WM
    [J]. JOURNAL OF PHOTOCHEMISTRY, 1984, 24 (03): : 249 - 263
  • [6] Luminescence properties of materials with Eu(III) complexes: Role of ligand, coligand, anion, and matrix
    Klonkowski, AM
    Lis, S
    Pietraszkiewicz, M
    Hnatejko, Z
    Czarnobaj, K
    Elbanowski, M
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (03) : 656 - 663
  • [7] Luminescence and energy transfer of the europium (III) tungstate obtained via the Pechini method
    Kodaira, CA
    Brito, HF
    Malta, OL
    Serra, OA
    [J]. JOURNAL OF LUMINESCENCE, 2003, 101 (1-2) : 11 - 21
  • [8] Mesquita ME, 1996, J CHEM RES-S, P120
  • [9] LUMINESCENT LANTHANIDE COMPLEXES AS PHOTOCHEMICAL SUPRAMOLECULAR DEVICES
    SABBATINI, N
    GUARDIGLI, M
    LEHN, JM
    [J]. COORDINATION CHEMISTRY REVIEWS, 1993, 123 (1-2) : 201 - 228
  • [10] Effects of dispersion by Gd3+ upon europium diphenylphosphinate luminescence
    Scarpari, SL
    Stucchi, EB
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 : 740 - 742
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