Metal catalyzed defunctionalization reactions

被引：88

作者：

Modak, Atanu ^{[1
]}

Maiti, Debabrata ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 01期

关键词：

C-O BONDS; SELECTIVE REDUCTIVE CLEAVAGE; CARBON-CYANO; ORGANIC HALIDES; ARYL ETHERS; POLYCHLORINATED-BIPHENYLS; HETEROGENEOUS CATALYSIS; PHENOL DERIVATIVES; MESYLOXY GROUPS; REDUCING AGENT;

D O I：

10.1039/c5ob01949d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Defunctionalization has a direct impact on the synthesis of value added products (e.g. biomass degradation). In synthetic chemistry it enables the functional group to act as a transient directing group. In this mini review, we have described the chronological development of metal assisted defunctionalization reactions from the stoichiometric to the catalytic stage with their application in synthetic organic chemistry. The proposed catalytic cycles of the transformations have been described to make this review comprehensible.

引用

页码：21 / 35

页数：15

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