CuII coordination polymers based on 5-methoxyisophthalate and flexible N-donor ligands: Structures and magnetic properties

被引：16
作者：
Chang, Xin-Hong [1 ]
Qin, Jian-Hua [1 ]
Ma, Lu-Fang [1 ]
Wang, Li-Ya [1 ,2 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
[2] Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2014年 / 212卷
基金：
中国国家自然科学基金;
关键词：
5-Methoxyisophthalic acid; 1,4-Bis(2-methylimidazol-1-yl)butane; 1,3-Bis(1Hbenzimidazolyl) propane; Magnetic properties; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; MICROPOROUS METAL; GAS-ADSORPTION; CO-LIGANDS; COMPLEXES; SEPARATION; CATALYSIS; ACID; DICARBOXYLATE;
D O I：
10.1016/j.jssc.2013.12.030
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three Cull coordination polymers, {[Cu-2(CH3O-ip)(2)(bmib)]}(n) (1), {[Cu-2(CH3O-ip)(2)(bmib)(2)]}(n) (2) and {[Cu (CH3O-ip)(bbin)]center dot 2H(2)O}(n) (3) (CH3O-H(2)ip is 5-methoxyisophthalic acid, brilib is 1,4-bis(2-methylimidazol-1-yl)butane and bbip is 1,3-bis(1H-benzimidazolyl)propane), have been synthesized by hydrothermal methods. Complexes 1-3 were structurally characterized by elemental analysis, infrared (IR) spectra and X-ray single-crystal diffraction. Complex 1 shows a 3D six-connected self-penetrating network based on paddlewheel secondary building units. Complex 2 has a 3-fold interpenetrating 3D diamond framework. Complex 3 possesses a 1D tube-like chain. Thermo-gravimetric and magnetic properties of 1-3 were also investigated. (C) 2014 Elsevier Inc. All rights reserved.
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页码：121 / 127
页数：7
相关论文
共 53 条
[1]  
[Anonymous], 1997, PROGRAM CRYSTAL STRU
[2]   Development and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture [J].
Bae, Youn-Sang ;
Snurr, Randall Q. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (49) :11586-11596
[3]   A New Series of CuII Coordination Polymers Derived from Bis-pyridyl-bis-urea Ligands and Various Dicarboxylates and Their Role in Methanolysis of Epoxide Ring-Opening Catalysis [J].
Banerjee, Subhabrata ;
Kumar, Dhurjati Prasad ;
Bandyopadhay, Sabyasachi ;
Adarsh, N. N. ;
Dastidar, Parthasarathi .
CRYSTAL GROWTH & DESIGN, 2012, 12 (11) :5546-5554
[4]   A microporous metal-organic framework with high stability for GC separation of alcohols from water [J].
Borjigin, Tsolmon ;
Sun, Fuxing ;
Zhang, Jinlei ;
Cai, Kun ;
Ren, Hao ;
Zhu, Guangshan .
CHEMICAL COMMUNICATIONS, 2012, 48 (61) :7613-7615
[5]   A Doubly Interpenetrated Metal-Organic Framework with Open Metal Sites and Suitable Pore Sizes for Highly Selective Separation of Small Hydrocarbons at Room Temperature [J].
Cai, Jianfeng ;
Yu, Jiancan ;
Xu, Hui ;
He, Yabing ;
Duan, Xing ;
Cui, Yuanjing ;
Wu, Chuande ;
Chen, Banglin ;
Qian, Guodong .
CRYSTAL GROWTH & DESIGN, 2013, 13 (05) :2094-2097
[6]   A series of 2D lanthanide (III) coordination polymers constructed from 2-(pyridin-3-yl)-1H-imidazole-4,5-dicarboxylate [J].
Cai, Song Liang ;
Zheng, Sheng Run ;
Fan, Jun ;
Tan, Jing Bo ;
Xiao, Tian Tian ;
Zhang, Wei-Guang .
JOURNAL OF SOLID STATE CHEMISTRY, 2011, 184 (12) :3172-3178
[7]   Microporous metal - Organic frameworks formed in a stepwise manner from luminescent building blocks [J].
Chandler, Brett D. ;
Cramb, David T. ;
Shimizu, George K. H. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (32) :10403-10412
[8]   New Zn-Aminotriazolate-Dicarboxylate Frameworks: Synthesis, Structures, and Adsorption Properties [J].
Chen, Kai-Jie ;
Lin, Rui-Biao ;
Liao, Pei-Qin ;
He, Chun-Ting ;
Lin, Jian-Bin ;
Xue, Wei ;
Zhang, Yue-Biao ;
Zhang, Jie-Peng ;
Chen, Xiao-Ming .
CRYSTAL GROWTH & DESIGN, 2013, 13 (05) :2118-2123
[9]   Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks [J].
Chen, Man-Sheng ;
Chen, Min ;
Takamizawa, Satoshi ;
Okamura, Taka-aki ;
Fan, Jian ;
Sun, Wei-Yin .
CHEMICAL COMMUNICATIONS, 2011, 47 (13) :3787-3789
[10]   Structure, adsorption and magnetic properties of chiral metal-organic frameworks bearing linear trinuclear secondary building blocks [J].
Chen, Zilu ;
Liu, Xianlin ;
Zhang, Chuanbing ;
Zhang, Zhong ;
Liang, Fupei .
DALTON TRANSACTIONS, 2011, 40 (09) :1911-1918
123456