Metal-based electrocatalytic conversion of CO2 to formic acid/formate

被引：150
作者：
Ding, Peng [1 ]
Zhao, Haitao [2 ]
Li, Tingshuai [2 ]
Luo, Yongsong [2 ]
Fan, Guangyin [2 ]
Chen, Guang [3 ]
Gao, Shuyan [4 ]
Shi, Xifeng [5 ]
Lu, Siyu [1 ]
Sun, Xuping [2 ]
机构：
[1] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450001, Henan, Peoples R China
[2] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Sichuan, Peoples R China
[3] Qufu Normal Univ, Key Lab Life Organ Anal, Key Lab Pharmaceut Intermediates & Anal Nat Med, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China
[4] Henan Normal Univ, Sch Mat Sci & Engn, Xinxiang 453007, Henan, Peoples R China
[5] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2020年 / 8卷 / 42期
基金：
中国国家自然科学基金;
关键词：
SELECTIVE ELECTROCHEMICAL REDUCTION; MESOPOROUS SNO2 NANOSHEETS; CARBON-DIOXIDE REDUCTION; GAS-DIFFUSION ELECTRODE; HIGH-EFFICIENCY; CATALYZED HYDROGENATION; MECHANISTIC INSIGHTS; TIN ELECTRODES; OXIDE LAYER; IN-SITU;
D O I：
10.1039/d0ta08393c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rapid increase of CO2 content in the atmosphere has caused serious environmental concern. To effectively alleviate the issue, it is of great significance to use electrocatalytic technology to convert CO2 into high value-added energy materials. In this minireview, we present the recent progress in the development of metal-based electrocatalysts for the electrocatalysis of CO2 to formic acid/formate. Firstly, we briefly study the possible reaction pathways and mechanisms of electrochemical reduction of CO2. Secondly, the emerging development of different types of metal-based electrocatalysts (homogeneous catalysts and heterogeneous catalysts) as high-performance catalysts is reviewed for improving process efficiency and productivity. Based on the insights, we summarize the current challenges and the future research directions of metal-based materials for the electrocatalytic reduction of CO2.
引用
收藏
页码：21947 / 21960
页数：14
相关论文
共 50 条
  • [41] Sequential Co-immobilization of Enzymes in Metal-Organic Frameworks for Efficient Biocatalytic Conversion of Adsorbed CO2 to Formate
    Li, Yan
    Wen, Liyin
    Tan, Tianwei
    Lv, Yongqin
    FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY, 2019, 7
  • [42] In Situ Bismuth Nanosheet Assembly for Highly Selective Electrocatalytic CO2 Reduction to Formate
    Peng, Chan-Juan
    Wu, Xin-Tao
    Zeng, Guang
    Zhu, Qi-Long
    CHEMISTRY-AN ASIAN JOURNAL, 2021, 16 (12) : 1539 - 1544
  • [43] Recent progress in structural modulation of metal nanomaterials for electrocatalytic CO2 reduction
    Yang, Chen-Huai
    Nosheen, Farhat
    Zhang, Zhi-Cheng
    RARE METALS, 2021, 40 (06) : 1412 - 1430
  • [44] Photo-/electrocatalytic approaches to CO2 conversion on Cu2O-based catalysts
    Zhao, Zixuan
    Wang, Hongtao
    Yu, Qi
    Roy, Soumendra
    Yu, Xiaohu
    APPLIED CATALYSIS A-GENERAL, 2023, 667
  • [45] A computational study of electrochemical CO2 reduction to formic acid on metal-doped SnO2
    Liu, Zhaochun
    Zong, Xue
    Vlachos, Dionisios G.
    Filot, Ivo A. W.
    Hensen, Emiel J. M.
    CHINESE JOURNAL OF CATALYSIS, 2023, 50 : 249 - 259
  • [46] Regulation Strategy of Nanostructured Engineering on Indium-Based Materials for Electrocatalytic Conversion of CO2
    Wu, Wenbo
    Tong, Yun
    Chen, Pengzuo
    SMALL, 2024, 20 (09)
  • [47] Deciphering Visible Light Photoreductive Conversion of CO2 to Formic Acid and Methanol Using Waste Prepared Material
    Zhang, Qian
    Lin, Cheng-Fang
    Chen, Bor-Yann
    Ouyang, Tong
    Chang, Chang-Tang
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2015, 49 (04) : 2405 - 2417
  • [48] Bismuth nanodendrites as a high performance electrocatalyst for selective conversion of CO2 to formate
    Zhong, Hexiang
    Qiu, Yanling
    Zhang, Taotao
    Li, Xianfeng
    Zhang, Huamin
    Chen, Xiaobo
    JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (36) : 13746 - 13753
  • [49] Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction
    Gotico, Philipp
    Leibl, Winfried
    Halime, Zakaria
    Aukauloo, Ally
    CHEMELECTROCHEM, 2021, 8 (18) : 3472 - 3481
  • [50] Recent Progress in the Theoretical Investigation of Electrocatalytic Reduction of CO2
    Tian, Ziqi
    Priest, Chad
    Chen, Liang
    ADVANCED THEORY AND SIMULATIONS, 2018, 1 (05)
12345