Metal-based electrocatalytic conversion of CO2 to formic acid/formate

被引：161

作者：

Ding, Peng ^{[1
]}

Zhao, Haitao ^{[2
]}

Li, Tingshuai ^{[2
]}

Luo, Yongsong ^{[2
]}

Fan, Guangyin ^{[2
]}

Chen, Guang ^{[3
]}

Gao, Shuyan ^{[4
]}

Shi, Xifeng ^{[5
]}

Lu, Siyu ^{[1
]}

Sun, Xuping ^{[2
]}

机构：

[1] Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Zhengzhou 450001, Henan, Peoples R China

[2] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Sichuan, Peoples R China

[3] Qufu Normal Univ, Key Lab Life Organ Anal, Key Lab Pharmaceut Intermediates & Anal Nat Med, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China

[4] Henan Normal Univ, Sch Mat Sci & Engn, Xinxiang 453007, Henan, Peoples R China

[5] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2020年 / 8卷 / 42期

基金：

中国国家自然科学基金;

关键词：

SELECTIVE ELECTROCHEMICAL REDUCTION; MESOPOROUS SNO2 NANOSHEETS; CARBON-DIOXIDE REDUCTION; GAS-DIFFUSION ELECTRODE; HIGH-EFFICIENCY; CATALYZED HYDROGENATION; MECHANISTIC INSIGHTS; TIN ELECTRODES; OXIDE LAYER; IN-SITU;

D O I：

10.1039/d0ta08393c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rapid increase of CO2 content in the atmosphere has caused serious environmental concern. To effectively alleviate the issue, it is of great significance to use electrocatalytic technology to convert CO2 into high value-added energy materials. In this minireview, we present the recent progress in the development of metal-based electrocatalysts for the electrocatalysis of CO2 to formic acid/formate. Firstly, we briefly study the possible reaction pathways and mechanisms of electrochemical reduction of CO2. Secondly, the emerging development of different types of metal-based electrocatalysts (homogeneous catalysts and heterogeneous catalysts) as high-performance catalysts is reviewed for improving process efficiency and productivity. Based on the insights, we summarize the current challenges and the future research directions of metal-based materials for the electrocatalytic reduction of CO2.

引用

页码：21947 / 21960

页数：14

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