Amplified photochemistry with slow photons

被引:351
作者
Chen, Jennifer I. L.
von Freymann, Georg
Choi, Sung Yeun
Kitaev, Vladimir
Ozin, Geoffrey A.
机构
[1] Univ Toronto, Dept Chem, Mat Chem Res Grp, Toronto, ON M5S 3H6, Canada
[2] Forschungszentrum Karlsruhe, Helmholtz Gemeinschaft, D-76021 Karlsruhe, Germany
[3] Wilfrid Laurier Univ, Dept Chem, Waterloo, ON N2L 3C5, Canada
关键词
D O I
10.1002/adma.200600588
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Slow photons in photonic crystals are shown to optically amplify the photoactivity of anatase TiO2 in an inverse opal structure. An enhancement in TiO2 absorption as a result of slow photons leads to a larger population of electronhole pairs and faster degradation of organic molecules. A remarkable twofold enhancement is achieved (see figure) when the energy of the slow photons is optimized with respect to the absorption edge of anatase.
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页码:1915 / +
页数:6
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