Tools for studying aqueous enantioselective lanthanide-catalyzed Mukaiyama aldol reactions

被引：15
作者：
Averill, Derek J. [1 ]
Allen, Matthew J. [1 ]
机构：
[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 12期
基金：
美国国家科学基金会;
关键词：
LEWIS-ACID CATALYSTS; SILYL ENOL ETHERS; LUMINESCENCE-DECAY; SPECTROSCOPIC CHARACTERIZATION; EUROPIUM(III) IONS; WATER-MOLECULES; MEDIA; COMPLEXES; LIGANDS; YTTERBIUM;
D O I：
10.1039/c4cy01117a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Enantioselective bond-forming reactions catalyzed by chiral lanthanide-based complexes are popular because of their Lewis acidity, solvent compatibility, reusability, and potential to catalyze reactions with high stereospecificity. The stereospecific outcomes of bond-forming reactions catalyzed by asymmetric lanthanide-based precatalysts depend on the coordination chemistry of the precatalysts that can be interrogated with X-ray crystal structures, luminescence measurements, NMR spectroscopy, and computational methods. This review is primarily focused on developments related to lanthanide-based precatalysts since the turn of the century and the techniques used to study coordination environments of lanthanide-based precatalysts for Mukaiyama aldol reactions in aqueous media.
引用
收藏
页码：4129 / 4137
页数：9
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