Effect of catalyst pattern geometry on the growth of vertically aligned carbon nanotube arrays

被引:52
作者
Jeong, Goo-Hwan [2 ,3 ]
Olofsson, Niklas [2 ]
Falk, Lena K. L. [4 ]
Campbell, Eleanor E. B. [1 ,2 ,5 ]
机构
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ Gothenburg, Dept Phys, SE-41296 Gothenburg, Sweden
[3] Kangwon Natl Univ, Dept Adv Mat Sci & Engn, Kangwon Do 200701, South Korea
[4] Chalmers, Dept Appl Phys, SE-41296 Gothenburg, Sweden
[5] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
CHEMICAL-VAPOR-DEPOSITION; NUCLEATION; CVD;
D O I
10.1016/j.carbon.2008.11.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the effect of catalyst pattern geometry on the growth behaviour of carbon nanotube (CNT) vertical arrays. Larger patterns are seen to produce longer CNT arrays. We show that this is predominantly related to the pattern size dependence of the number of walls and relate this to the local availability of carbon feedstock species. In addition, the vertical alignment of CNT pillar arrays is seen to depend on the pattern design, in particular the relationship between the pillar dimension and the inter-pillar spacing. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:696 / 704
页数:9
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