Methane reforming with carbon dioxide over La-Nix-Ce1-x mixed oxide catalysts

被引：0

作者：

Sagar, T. V. ^{[1
]}

Sreelatha, N. ^{[1
]}

Hanmant, G. ^{[2
]}

Upendar, K. ^{[1
]}

Lingaiah, N. ^{[1
]}

Rao, Kamaraju Seetha Rama ^{[1
]}

Satyanarayana, C. V. V. ^{[2
]}

Reddy, I. A. K. ^{[3
]}

Prasad, P. S. Sai ^{[1
]}

机构：

[1] Indian Inst Chem Technol, CSIR, Hyderabad 500007, Andhra Pradesh, India

[2] Natl Chem Lab, CSIR, Pune 411008, Maharashtra, India

[3] Natl Inst Technol, Warangal 506004, Andhra Pradesh, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2014年 / 53卷 / 4-5期

关键词：

Catalysts; Carbon dioxide reforming; Dry reforming; Hydrothermal synthesis; Methane reforming; Mixed oxides; Nickel; Lanthanum; Cerium; HYDROGEN; NI; SYSTEM; CO; PERFORMANCE; TRANSITION; OXIDATION; ALUMINA; METALS; SYNGAS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

La-Ni-x-Ce1-x mixed oxide (0 <= x <= 1) catalysts have been hydrothermally prepared, characterized by physico-chemical techniques and evaluated for CO2 reforming of methane. High conversions are achieved for both methane and carbon dioxide over the LaNi0.6Ce0.4O3 catalyst tested under the conditions of CO2/CH4/N-2 ratio of 80/80/80. (total flow rate = 240 mL/min), space velocity of 28,800 h(-1) and at a temperature of 800 degrees C. The H-2/CO ratio in the syngas is stable at 0.93 +/- 0.02. Exchanging Ni with Ce, rather than with La as reported in the literature, appears to be a better option for the improved performance of the catalysts.

引用

页码：478 / 483

页数：6

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