Crystal structure, thermal analysis and IR spectrometric investigation of bis(o-anisidinium) sulfate (C7H10NO)2SO4

被引：11

作者：

Chtioui, Ahlem ^{[1
]}

BenHamada, Latifa ^{[1
]}

Jouini, Amor ^{[1
]}

机构：

[1] Univ Ctr, Fac Sci Monastir, Dept Chim, Chim Solide Lab, Monastir 5019, Tunisia

来源：

MATERIALS RESEARCH BULLETIN | 2009年 / 44卷 / 03期

关键词：

Chemical synthesis; X-ray diffraction; Infrared spectroscopy;

D O I：

10.1016/j.materresbull.2008.07.012

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Chemical preparation, X-ray single-crystal, thermal behaviour, and IR spectroscopy investigations are given for a new organic cation sulfate (C7H10NO)(2)SO4 (denoted BOAS) in the solid state. This compound crystallizes in the monoclinic space group P2(1)/c. The unit cell dimensions are: a = 7.010(3)angstrom, b = 11.142(5)angstrom, c = 20.770(8)angstrom, beta = 95.27(3)degrees with upsilon = 1615.4(12)angstrom(3) and Z = 4. The structure has been solved using a direct method and refined to a reliability R factor of 0.047. The title compound consists of a framework of isolated SO4 tetrahedral interleaved with organic molecules. so as to build isolated ribbons parallel to a-axis. In the present work, we describe the crystal structure, thermal behaviour and IR analysis of this new compound. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：560 / 565

页数：6

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