Recognition of benzene, toluene and xylene using TGS array integrated with linear and non-linear classifier

被引:29
作者
Szczurek, A [1 ]
Maciejewska, M [1 ]
机构
[1] Wroclaw Tech Univ, Ecolog & Atmosphere Protect Grp, Inst Environm Protect Engn, PL-50377 Wroclaw, Poland
关键词
sensor array; DFA; RBF; VOC;
D O I
10.1016/j.talanta.2004.03.036
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Three volatile organic compounds (VOCs): benzene, toluene and xylene were measured with an array of six Taguchi gas sensors in the air with variable humidity content. The recognition of single compounds was performed, based on measurement results. The principal component analysis (PCA) pointed at humidity as the main classification factor in the measurement data set. The linear discriminant analysis (LDA) was applied to overcome this drawback and enforce classification with respect to benzene, toluene or xylene. It was shown that discriminant function analysis (DFA), which is an LDA method allowed for 100% success rate in test samples recognition of benzene. It did not allow for accurate recognition of test samples of toluene or xylene. Following, the non-linear classifier, radial basis function neural network (RBFNN) was applied. A specific configuration of input 's was found, which provided for successful recognition of each single compound: benzene, toluene or xylene in air with variable humidity content. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:609 / 617
页数:9
相关论文
共 18 条
[11]   Strategies to avoid VOC cross-sensitivity of SnO2-based CO sensors [J].
Schweizer-Berberich, M ;
Strathman, S ;
Weimar, U ;
Sharma, R ;
Seube, A ;
Peyre-Lavigne, A ;
Göpel, W .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 58 (1-3) :318-324
[12]   A comparison study of chemical sensor array pattern recognition algorithms [J].
Shaffer, RE ;
Rose-Pehrsson, SL ;
McGill, RA .
ANALYTICA CHIMICA ACTA, 1999, 384 (03) :305-317
[13]  
SZCZUREK A, 2003, ENV PROTECT ENG, V2, P125
[14]  
SZCZUREK A, 1999, CHEM INZYNIERIA EKOL, V10, P1055
[15]   Quantitative and qualitative analysis of VOCs mixtures by means of a microsensors array and different evaluation methods [J].
Taurino, AM ;
Distante, C ;
Siciliano, P ;
Vasanelli, L .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :117-125
[16]   Application of Radial Basis Functions - Partial Least Squares to non-linear pattern recognition problems: Diagnosis of process faults [J].
Walczak, B ;
Massart, DL .
ANALYTICA CHIMICA ACTA, 1996, 331 (03) :187-193
[17]  
WEBB A, 1999, STAT PATTERN RECOGNI, P227
[18]  
2003, PERMISSIBLE LEVELS A