Octadehydrodibenzo[12]annulene-Based Organogels: Two Methyl Ester Groups Prevent Crystallization and Promote Gelation

被引:56
作者
Hisaki, Ichiro [1 ]
Shigemitsu, Hajime [1 ]
Sakamoto, Yuu [1 ]
Hasegawa, Yasuchika [2 ]
Okajima, Yasuo [2 ]
Nakano, Kazunori [3 ]
Tohnai, Norimitsu [1 ]
Miyata, Mikiji [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan
[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara, Japan
[3] Nagoya Municipal Ind Res Inst, Nagoya, Aichi, Japan
关键词
annulenes; dipole-dipole interactions; gels; self-assembly; supramolecular chemistry; MOLECULAR NETWORKS; PI-ORGANOGELS; DERIVATIVES; ELUCIDATION; ASSEMBLIES; ACCEPTORS; PACKING; SIZE;
D O I
10.1002/anie.200900501
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A boomerang-shaped organic gelator, a dehydrobenzo [12]annulene derivative with two methyl ester groups (see picture), successfully forms an organogel in various organic solvents. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5465 / 5469
页数:5
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