Spontaneous vesicle formation in a deep eutectic solvent

被引:73
|
作者
Bryant, Saffron J. [1 ]
Atkin, Rob [2 ]
Warr, Gregory G. [1 ]
机构
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
[2] Univ Newcastle, Discipline Chem, Newcastle, NSW 2308, Australia
基金
澳大利亚研究理事会;
关键词
SODIUM DODECYL-SULFATE; IONIC LIQUIDS; CHOLINE CHLORIDE/UREA; PHASE-TRANSITIONS; TEMPERATURE; BILAYERS; DEPENDENCE; MECHANISM; MEMBRANES; BEHAVIOR;
D O I
10.1039/c5sm02660a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Solvent penetration experiments and small-angle X-ray scattering reveal that phospholipids dissolved in a deep eutectic solvent (DES) spontaneously self-assemble into vesicles above the lipid chain melting temperature. This means DESs are one of the few nonaqueous solvents that mediate amphiphile self-assembly, joining a select set of H-bonding molecular solvents and ionic liquids.
引用
收藏
页码:1645 / 1648
页数:4
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