Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal

被引：58
作者：
Jang, Doo Ok [1 ]
Moon, Kyung Soo
Cho, Dae Hyan
Kim, Joong-Gon
机构：
[1] Yonsei Univ, Dept Chem, Wonju 220710, South Korea
[2] Yonsei Univ, Ctr Bioact Mol Hybrids, Seoul 120749, South Korea
[3] Hanwha Chem R&D Ctr, Div Biotechnol, Taejon 305345, South Korea
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 34期
关键词：
Friedel-Crafts acylation; sulfonylation; indium; aromatic ketones; acid chlorides;
D O I：
10.1016/j.tetlet.2006.06.099
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Friedel-Crafts acylation of activated benzenes with various aromatic and aliphatic acid chlorides was studied in the presence of indiurn metal. The reaction was accomplished in high isolated yields under solvent or solvent-less conditions. The method is also applicable for preparing diaryl sulfones from aromatic compounds and aryl sulfonyl chlorides. (c) 2006 Elsevier Ltd. All rights reserved.
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收藏
页码：6063 / 6066
页数：4
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