Dichlorocarbene adducts of alkyl enol ethers as precursors to furans:: application to a total synthesis of the furanosesquiterpene (±)-pallescensin A

被引：28
作者：
Foot, Jonathan S. [1 ]
Phillis, Andrew T. [1 ]
Sharp, Phillip P. [1 ]
Willis, Anthony C. [1 ]
Banwell, Martin G. [1 ]
机构：
[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 0200, Australia
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 38期
基金：
澳大利亚研究理事会;
关键词：
cyclopropene; dichlorocyclopropane; furan; furanosesquiterpene; pallescensin A; Wieland-Miescher ketone;
D O I：
10.1016/j.tetlet.2006.07.068
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel method for annulating furans to ketones, involving treatment of the dichlorocarbene adduct of the derived methyl enol ether with base, has been exploited in the synthesis of the title natural product 1 from the known trans-decalone 2. Crown Copyright (c) 2006 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：6817 / 6820
页数：4
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