One-Pot, Clean Synthesis of Vanillic Acid from Ferulic Acid

被引：24

作者：

Delisi, Riccardo ^{[1
]}

Ciriminna, Rosaria ^{[1
]}

Parrino, Francesco ^{[2
]}

Palmisano, Leonardo ^{[2
]}

Xu, Yi-Jun ^{[3
]}

Pagliaro, Mario ^{[1
]}

机构：

[1] Inst Studio Mat Nanostrutturati, CNR, Via U. La Malfa 153, I-90146 Palermo, Italy

[2] Univ Studi Palermo, DEIM, Schiavello Grillone Photocatalysis Grp, Palermo, Italy

[3] Fuzhou Univ, Dept Chem & Chem Engn, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

来源：

CHEMISTRYSELECT | 2016年 / 1卷 / 03期

关键词：

vanillic acid; vanillin; ferulic acid; oxidation; bismuth tungstate; VISIBLE-LIGHT; OXIDATION; BI2WO6; AMMOXIDATION; WATER;

D O I：

10.1002/slct.201600111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ferulic acid dissolved in water is selectively oxidized to vanillic acid in high yield (approximate to 60%) under remarkably mild and green conditions, namely at room temperature with air as primary oxidant, over a catalytic amount of nanostructured Bi2WO6. The process is general and opens the route to the selective oxidation of natural substances into derivatives of significant applicative relevance.

引用

页码：626 / 629

页数：4

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