A stable second-order NLO and luminescent Cd(II) complex based on 6-hydroxynicotinic acid

被引：29

作者：

He, Yin-Hua ^{[1
]}

Lan, You-Zhao ^{[1
]}

Zhan, Cai-Hong ^{[1
]}

Feng, Yun-Long ^{[1
]}

Su, Hong ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 06期

关键词：

6-Hydroxynicotinic acid; Cadmium complex; Hydrothermal synthesis; Luminescent property; NLO-active; NONLINEAR-OPTICAL PROPERTIES; COORDINATION NETWORKS; DESIGN; ZINC; PHOTOLUMINESCENCE; FRAMEWORK; POLYMERS; LIGAND;

D O I：

10.1016/j.ica.2008.09.031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Employing an unsymmetrical 6-hydroxynicotinic acid as a bridging ligand, we have prepared a new NLO-active two-dimensional cadmium coordination polymer [Cd-8(nicO)(8)(phen)(8) center dot (H2O)](n) (1) (H(2)nicO = 6-hydroxynicotinic acid, phen = 1,10-phenanthroline) under hydrothermal condition. At room temperature, 1 shows strong fluorescent emission bands in the solid state and a SHG efficiency of about 8 times that of KDP (KH2PO4). On the basis of TG/DTA analyses, the structure is thermally stable up to 370 degrees C. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：1952 / 1956

页数：5

共 43 条

[1]

[Anonymous], 1987, Nonlinear Optical Properties of Organic a. Molecules and Crystals

[2]

[Anonymous], 2017, J MOL STRUCT, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014

[3] Nonlinear optically active polymeric coordination networks based on metal m-pyridylphosphonates [J].