Removal of Acidic and Basic Dyes from Water using Crosslinked Polystyrene Based Quaternary Ethyl Piperazine Resin

被引:14
|
作者
Bildik, Fatih [1 ]
Turan, Gulcin Torunoglu [1 ]
Barim, Gamze [2 ]
Senkal, Bahire Filiz [1 ]
机构
[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey
[2] Adiyaman Univ, Dept Chem, Adiyaman, Turkey
关键词
dye removal; polymeric sorbent; quaternary amine functional resin; functional polymer; REACTIVE DYES; AQUEOUS-SOLUTIONS; METHYLENE-BLUE; TEXTILE DYES; ADSORPTION; KINETICS; BIOSORPTION; SORPTION; CARBONS; VIOLET;
D O I
10.1080/01496395.2014.906462
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, a beaded polymer with quaternary amine functions was prepared in two steps, starting from poly (vinyl benzyl chloride-ethylene glycol dimethacrylate) (PVBC) based beads, according to the synthetic protocol; modification of ethyl piperazine with PVBC (EP-PS), and quaternization of ethylpiperazine modified beads with chloroacetic acid (QEP-PS). The QEP-PS resin was used for the removal of reactive red 120 as an acidic dye and malachite green chloride as a basic dye. Dye extraction experiments were carried out simply by contacting wetted sorbent samples with aqueous dye solutions at room temperature. Capacities were determined by colorimetric analysis of the residual dye contents. The resin showed that reasonable high dye sorption capacity (0.34-0.41 g per gram of dry resin) was achieved. The adsorption conditions (initial dye concentration and pH) were varied to evaluate the mechanism of adsorption of both basic dyes and acidic dyes on the prepared resin. This material is also able to remove both the anionic dye and cationic dyes completely even from highly diluted aqueous dye solutions.
引用
收藏
页码:1700 / 1705
页数:6
相关论文
共 50 条
  • [1] Removal of dyes from water using crosslinked aminomethane sulfonic acid based resin
    Kaner, Damla
    Sarac, Ayfer
    Senkal, Bahire Filiz
    ENVIRONMENTAL GEOCHEMISTRY AND HEALTH, 2010, 32 (04) : 321 - 325
  • [2] Removal of dyes from water using crosslinked aminomethane sulfonic acid based resin
    Damla Kaner
    Ayfer Saraç
    Bahire Filiz Şenkal
    Environmental Geochemistry and Health, 2010, 32 : 321 - 325
  • [3] Adsorption of Dyes from Acidic Wastewater by Crosslinked Chitosan Resin
    Huang, Zhonghua
    Zou, Yan
    Yuan, Fang
    Li, Weijing
    Pu, Xue
    NEW MATERIALS, APPLICATIONS AND PROCESSES, PTS 1-3, 2012, 399-401 : 1363 - 1366
  • [4] Simultaneous removal of acidic dyes on binary mixture from aqueous solutions by magnetic basic resin
    Karanfil, Devlet Yeter
    Coskun, Ramazan
    Delibas, Ali
    JOURNAL OF APPLIED POLYMER SCIENCE, 2024, 141 (44)
  • [5] Boron removal from water and wastewater using new polystyrene-based resin grafted with glycidol
    Kluczka, Joanna
    Korolewicz, Teofil
    Zolotajkin, Maria
    Adamek, Jakub
    WATER RESOURCES AND INDUSTRY, 2015, 11 (46-57) : 46 - 57
  • [6] Preparation of Dicarboxylic Acid Containing Sulfonamide Based Resin and Removal of Basic Dyes
    Yavuz, Erdem
    Tekin, Emir Tugrul
    Kandaz, Mehmet
    Senkal, Bahire Filiz
    SEPARATION SCIENCE AND TECHNOLOGY, 2010, 45 (05) : 687 - 691
  • [7] Highly efficient and rapid Pb(ii) removal from acidic wastewater using superhydrophilic polystyrene phosphate resin
    Sun, Junhua
    Zhao, Xiuxian
    Sun, Guoxin
    Zhao, Heng
    Yang, Zhen
    Yan, Liangguo
    Jiang, Xuchuan
    Cui, Yu
    NEW JOURNAL OF CHEMISTRY, 2022, 46 (34) : 16567 - 16575
  • [8] Evaluation of polystyrene anion exchange resin for removal of reactive dyes from aqueous solutions
    Greluk, Magdalena
    Hubicki, Zbigniew
    CHEMICAL ENGINEERING RESEARCH & DESIGN, 2013, 91 (07): : 1343 - 1351
  • [9] Evaluation of the efficacy of halloysite nanotubes in the removal of acidic and basic dyes from aqueous solution
    Ngulube, Tholiso
    Gumbo, Jabulani Ray
    Masindi, Vhahangwele
    Maity, Arjun
    CLAY MINERALS, 2019, 54 (02) : 197 - 207
  • [10] Application of magnetic isothiouronium polyurethane sorbent for the removal of acidic and basic dyes from wastewater
    Moawed, Elhossein A.
    El-Hagrasy, Maha A.
    Farhat, Asmaa A. M.
    JOURNAL OF CLEANER PRODUCTION, 2017, 157 : 232 - 242