Magnetite-coated metal foams as one-body catalysts for Fenton-like reactions

被引:8
|
作者
Thi May Do [1 ,2 ]
Byun, Ji Young [1 ]
Kim, Sang Hoon [1 ,2 ]
机构
[1] Korea Inst Sci & Technol, Ctr Mat Architecturing, Seoul 136791, South Korea
[2] Univ Sci & Technol, Dept Nanomat Sci & Engn, Daejeon 305350, South Korea
关键词
Fenton process; Metal foam; Magnetite; Methylene blue; Advanced oxidation process; OXIDATION; NANOPARTICLES; KINETICS;
D O I
10.1007/s11164-016-2440-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The possibility of preparing one-body catalyst was investigated for heterogeneous Fenton-like reactions by coating magnetite powder on metal foams. Up to 10 wt% magnetite could be coated onto metal foams with strong enough adhesion. The catalytic efficiency of the catalyst was investigated using a model reaction of methylene blue degradation at a circumneutral pH using H2O2 as the source of OH radicals and oxalic acid as the chelating agent. Comparison with conventional magnetite powder indicated that the catalytic efficiency of magnetite-coated metal foam was better than that of the powder only due to a larger exposed surface area. After treatment, separation of the one-body catalyst was easier and cleaner than that of conventional magnetite powder catalyst.
引用
收藏
页码:3481 / 3492
页数:12
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