Study of Cao Sorbent for CO2 Capture from Flue Gases

被引:4
作者
Mofarahi, Masoud [1 ]
Roohi, Parham [1 ]
Farshadpoor, Foroogh [1 ]
机构
[1] Persian Gulf Univ, Dept Chem Engn, Bushehr, Iran
来源
ICHEAP-9: 9TH INTERNATIONAL CONFERENCE ON CHEMICAL AND PROCESS ENGINEERING, PTS 1-3 | 2009年 / 17卷
关键词
CALCIUM-OXIDE; BED;
D O I
10.3303/CET0917068
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study focuses on the CO(2) sorption from a synthetic gas mixture (3% CO(2)-97% N(2)) by the carbonation reaction of CaO. Experiments are carried out in a U-tube fixed bed at high temperature. The experiments are designed on the base of CO(2) adsorption dependency on the bed temperature and gas flow rate in the carbonation reaction. The CO(2) concentration profile at the outlet of The bed, is recorded by the calibrated CO(2) gas sensor (solid electrolyte type). In addition, the conversion of CaO to CaCo(3) is obtained in according to the bed temperature and after that, the results are applied in a proposed model. Base on this model, carbonation reaction in the fixed bed predict by the fast chemical reaction control regime. The activation energy is estimated to about 65.84, KJ/mol that it is in agreement with the other values found in the previous work for the chemical reaction control regime.
引用
收藏
页码:403 / 408
页数:6
相关论文
共 6 条
[1]   Capture of CO2 from combustion gases in a fluidized bed of CaO [J].
Abanades, JC ;
Anthony, EJ ;
Lu, DY ;
Salvador, C ;
Alvarez, D .
AICHE JOURNAL, 2004, 50 (07) :1614-1622
[2]   Pore-size and shape effects on the recarbonation performance of calcium oxide submitted to repeated calcination/recarbonation cycles [J].
Alvarez, D ;
Abanades, JC .
ENERGY & FUELS, 2005, 19 (01) :270-278
[3]   Carbonation-calcination cycle using high reactivity calcium oxide for carbon dioxide separation from flue gas [J].
Gupta, H ;
Fan, LS .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (16) :4035-4042
[4]  
Metz B, 2005, SPECIAL REPORT CARBO
[5]   A technical, economic, and environmental assessment of amine-based CO2 capture technology for power plant greenhouse gas control [J].
Rao, AB ;
Rubin, ES .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (20) :4467-4475
[6]   A twin fluid-bed reactor for removal of CO2 from combustion processes [J].
Shimizu, T ;
Hirama, T ;
Hosoda, H ;
Kitano, K ;
Inagaki, M ;
Tejima, K .
CHEMICAL ENGINEERING RESEARCH & DESIGN, 1999, 77 (A1) :62-68