Conductivity Studies of Blend Polymer Electrolyte System Irradiated with Swift Heavy O6+ ion beam

被引:2
作者
Dave, Gargi [1 ]
Kanchan, D. K. [1 ]
Singh, F. [2 ]
机构
[1] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Phys, Solid State Ion & Glass Res Lab, Vadodara 390002, India
[2] Inter Univ Accelerator Ctr, Aruna Asaf Ali Marg, New Delhi 110067, India
来源
62ND DAE SOLID STATE PHYSICS SYMPOSIUM | 2018年 / 1942卷
关键词
D O I
10.1063/1.5029218
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Effect of swift heavy ion irradiation on conductivity of blend electrolyte system [(PEO50:PAM(50)) +x%(NaCF3SO3), x=5, 7.5, 10, 12.5, 15, 17.5] with O6+ ion at four different fluences is investigated. The samples are prepared using solution cast technique and films are subjected to irradiation at room temperature. Conductivity is measured for pristine and irradiated sample as a function of frequency in the range 2 Hz - 2MHz from ambient temperature up to 338 K. It is observed that conductivity increases with thence. Highest conductivity value is found to be 3.2375x10(-4) S/cm at 338 K for fluence of 1x 10(12) ions/cm(2) for sample containing 17.5 wt% NaCF3SO3. SEM and X-ray diffraction techniques have been conducted for the blend electrolytes before and after irradiation to completely understand the changes in the surface morphology.
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页数:4
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共 9 条
[1]  
Alexander L. E., 1969, XRAY DIFFRACTION MET, P379
[2]  
Cullity B.D., 2001, Elements of X-Ray Diffraction Fraction, Vsecond, P99
[3]   COMPLEXES OF ALKALI-METAL IONS WITH POLY(ETHYLENE OXIDE) [J].
FENTON, DE ;
PARKER, JM ;
WRIGHT, PV .
POLYMER, 1973, 14 (11) :589-589
[4]   Ac-electrical conductivity of poly(propylene) before and after X-ray irradiation [J].
Gaafar, M .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2001, 174 (04) :507-511
[5]   Dielectric spectra of LiTFSI - doped chitosan/PEO blends [J].
Idris, N. H. ;
Senin, H. B. ;
Arof, A. K. .
IONICS, 2007, 13 (04) :213-217
[6]   Investigations on the effect of complexation of NaF salt with polymer blend (PEO/PVP) electrolytes on ionic conductivity and optical energy band gaps [J].
Kumar, K. Kiran ;
Ravi, M. ;
Pavani, Y. ;
Bhavani, S. ;
Sharma, A. K. ;
Rao, V. V. R. Narasimha .
PHYSICA B-CONDENSED MATTER, 2011, 406 (09) :1706-1712
[7]   An experimental and theoretical correlation to account for the effect of LiPF6 concentration on the ionic conductivity of poly(poly (ethylene glycol) methacrylate) [J].
Nava, D. P. ;
Guzman, G. ;
Vazquez-Arenas, J. ;
Cardoso, J. ;
Gomez, B. ;
Gonzalez, I. .
SOLID STATE IONICS, 2016, 290 :98-107
[8]   Morphology, chemical interaction, and conductivity of a PEO-ENR50 based on solid polymer electrolyte [J].
Noor, S. A. M. ;
Ahmad, A. ;
Talib, I. A. ;
Rahman, M. Y. A. .
IONICS, 2010, 16 (02) :161-170
[9]   Effect of electron beam irradiation on polymer electrolytes: Change in morphology, crystallinity, dielectric constant and AC conductivity with dose [J].
Raghu, S. ;
Kilarkaje, Subramanya ;
Sanjeev, Ganesh ;
Nagaraja, G. K. ;
Devendrappa, H. .
RADIATION PHYSICS AND CHEMISTRY, 2014, 98 :124-131