Microwave-assisted dehydration of fructose and inulin to HMF catalyzed by niobium and zirconium phosphate catalysts

被引：118
作者：
Antonetti, Claudia [1 ,2 ]
Melloni, Mattia [3 ]
Licursi, Domenico [1 ]
Fulignati, Sara [1 ]
Ribechini, Erika [1 ]
Rivas, Sandra [4 ]
Carlos Parajo, Juan [4 ]
Cavani, Fabrizio [2 ,3 ]
Galletti, Anna Maria Raspolli [1 ,2 ]
机构：
[1] Univ Pisa, Dept Chem & Ind Chem, Via G Moruzzi 13, I-56124 Pisa, Italy
[2] Consorzio INSTM, Via Giusti 9, I-50121 Florence, Italy
[3] Univ Bologna, Dipartimento Chim Ind Toso Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy
[4] Univ Vigo, Dept Chem Engn, Campus Ourense, Orense 32004, Spain
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2017年 / 206卷
关键词：
Fructose; 5-Hydroxymethyl-2-furaldehyde; Phosphate acid catalysts; Microwaves; Response surface methodology; SOLID ACID CATALYSTS; PINUS-PINASTER WOOD; LEVULINIC ACID; 5-HYDROXYMETHYLFURFURAL HMF; HETEROGENEOUS ZIRCONIUM; SUSTAINABLE PRODUCTION; GAMMA-VALEROLACTONE; SUBCRITICAL WATER; GIANT REED; CONVERSION;
D O I：
10.1016/j.apcatb.2017.01.056
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
5-Hydroxymethyl-2-furaldehyde (HMF) is a key bio-based platform for the production of renewable monomers and bio-fuels. However, most of its syntheses are carried out under not sustainable conditions. In this work, the production of HMF from fructose and inulin was investigated following the Green Chemistry principles, adopting aqueous medium, appreciable substrate concentration (10wt%), low loading of heterogeneous acid catalyst (niobium or zirconium phosphate) and microwave heating. Both the catalysts resulted very active and promising, in particular zirconium phosphate and the performances were related to their different acid characteristics. The optimization of HMF synthesis with zirconium phosphate was also supported by a statistical modelling, which shows that the highest yield to HMF (about 40 mol%) is ascertained at high temperature (190 degrees C) and short reaction time (8 min). The catalysts resulted recyclable maintaining their starting activity almost unchanged. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：364 / 377
页数：14
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