Poly[[[(1,10-phenanthroline-κ2N,N′)zinc(II)]-μ3-5-hydroxyisophthalato-κ4O,O′:O":O"′]monohydrate]

被引：11

作者：

Cao, XY ^{[1
]}

Zhang, JA ^{[1
]}

Kang, Y ^{[1
]}

Cheng, JK ^{[1
]}

Li, ZJ ^{[1
]}

Wang, XQ ^{[1
]}

Wen, YH ^{[1
]}

Yao, YG ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S010827010401056X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, {[Zn(C8H4O5)(C12H8N2)].H2O}(n) or {[Zn(OH-BDC)(phen)].H2O}(n) (where OH-H2BDC is 5-hydroxyisophthalic acid and phen is 1,10-phenanthroline), the Zn atoms are coordinated by two N atoms from the phen ligands and by four O atoms from hydroxyisophthalate ligands in a highly distorted octahedral geometry, with Zn-O distances in the range 2.042 (4)-2.085 (5) Angstrom and Zn-N distances of 2.133 (5) and 2.137 (5) Angstrom. The {[Zn(OHBDC)(phen)].H2O}(n) infinite zigzag polymer forms a helical chain of [Zn-2(OH-BDC)(2)](n) units. Face-to-face pi-pi interactions (3.60-3.75 Angstrom) occur between two phen rings belonging to the same helical chain. Consolidation of the packing structure is achieved by O-H...O hydrogen-bonding interactions between the carboxylate O atoms, the hydroxyl group and the water molecule, forming two-dimensional sheets.

引用

页码：M350 / M352

页数：3

共 17 条

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