Synthesis, characterization, and near-infrared luminescent properties of the ternary thulium complex covalently bonded to mesoporous MCM-41

被引：21
作者：
Feng, Jing [1 ,2 ]
Song, Shu-Yan [1 ,2 ]
Xing, Yan [1 ]
Zhang, Hong-Jie [1 ]
Li, Zhe-Feng [1 ,2 ]
Sun, Li-Ning [1 ]
Guo, Xian-Min [1 ,2 ]
Fan, Wei-Qiang [1 ,2 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2009年 / 182卷 / 03期
基金：
中国国家自然科学基金;
关键词：
MCM-41; Thulium complex; Covalently bonded; Near-infrared luminescence; Optical telecommunication; LANTHANIDE COMPLEXES; HYBRID MATERIALS; LIGHT-EMISSION; SILICA; FLUORESCENCE; CHANNELS; METAL;
D O I：
10.1016/j.jssc.2008.11.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of a ternary Tm(DBM)(3)phen complex (DBM - dibenzoylmethane; phen = 1. 10-phenanthroline) and the synthesis of hybrid mesoporous material in which the complex covalently bonded to mesoporous MCM-41 are reported. Crystal data: Tm(DBM)(3)phen C59H47N2O7Tm, monoclinic P21/c, a = 19.3216(12) A, b = 10.6691(7) A, c = 23.0165(15)A, alpha = 90, beta = 91.6330(10), gamma = 90, V = 4742.8(5) A(3), Z = 4. The properties of the Tm(DBM)(3)phen complex and the corresponding hybrid mesoporous material [Tm(DBM)(3)phen-MCM-41] have been studied. The results reveal that the Tm(DBM)(3)phen complex is successfully covalently bonded to MCM-41. Both Tm(DBM)(3)phen complex and Tm(DBM)3phen-MCM-41 display typical near-infrared (NIR) luminescence upon excitation at the maximum absorption of the ligands, which contributes to the efficient energy transfer from the ligands to the Tm3+ ion, an antenna effect, The full width at half maximum (FWHM) centered at 1474 nm in the emission Spectrum of Tm(DBM)(3)phen-MCM-41 is 110nm, which is the potential candidate of broadening amplification band from C band (1530-1560 nm) to S+ band (1450-1480 nm) in optical area. (C) 2008 Elsevier Inc. All rights reserved.
引用
收藏
页码：435 / 441
页数：7
相关论文
共 55 条
[1]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[2]  
Bekiari V, 1998, ADV MATER, V10, P1455, DOI 10.1002/(SICI)1521-4095(199812)10:17<1455::AID-ADMA1455>3.0.CO
[3]  
2-D
[4]   A luminescent tris(2-thenoyltrifluoroacetonato) europium(III) complex covalently linked to a 1,10-phenanthroline-functionalised sol-gel glass [J].
Binnemans, K ;
Lenaerts, P ;
Driesen, K ;
Görller-Walrand, C .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (02) :191-195
[5]   Lanthanide-containing liquid crystals and surfactants [J].
Binnemans, K ;
Görller-Walrand, C .
CHEMICAL REVIEWS, 2002, 102 (06) :2303-2345
[6]   Fine-tuning of the chromaticity of the emission color of organic-inorganic hybrids co-doped with EuIII, TbIII, and TmIII [J].
Carlos, LD ;
Ferreira, RAS ;
Rainho, JP ;
Bermudez, VD .
ADVANCED FUNCTIONAL MATERIALS, 2002, 12 (11-12) :819-823
[7]   Ordered porous materials for emerging applications [J].
Davis, ME .
NATURE, 2002, 417 (6891) :813-821
[8]   Ordered mesoporous and microporous molecular sieves functionalized with transition metal complexes as catalysts for selective organic transformations [J].
De Vos, DE ;
Dams, M ;
Sels, BF ;
Jacobs, PA .
CHEMICAL REVIEWS, 2002, 102 (10) :3615-3640
[9]   Near-infrared luminescence of lanthanide calcein and lanthanide dipicolinate complexes doped into a silica-PEG hybrid material [J].
Driesen, K ;
Van Deun, R ;
Görller-Walrand, C ;
Binnemans, K .
CHEMISTRY OF MATERIALS, 2004, 16 (08) :1531-1535
[10]   The lanthanides as luminescent probes in investigations of biochemical systems [J].
Elbanowski, M ;
Makowsaka, B .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1996, 99 (2-3) :85-92
123456