Ignition of hydrogen-methane-air mixtures over Pd foil at atmospheric pressure

被引：9
|
作者：
Rubtsov, Nikolai M. [1 ]
Chernysh, Victor I. [1 ]
Tsvetkov, Georgii I. [1 ]
Troshin, Kirill Ya. [2 ]
Shamshin, Igor O. [2 ]
机构：
[1] Russian Acad Sci, Inst Struct Macrokinet & Mat Sci, Chernogolovka 142432, Moscow Region, Russia
[2] Russian Acad Sci, NN Semenov Inst Chem Phys, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2019年 / 29卷 / 04期
关键词：
SUPPORTED PALLADIUM; COMBUSTION;
D O I：
10.1016/j.mencom.2019.07.039
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ignition temperature of a mixture of 40% H-2 in air over Pd (70 degrees C, 1 atm) is similar to 200 degrees C lower than that over a Pt surface (260 degrees C, 1 atm). In addition, Pd foil ignites mixtures (30-60% H-2 + 70-40% CH4)(stoich) + air; Pt foil cannot ignite these up to 450 degrees C. The effective activation energy of ignition over Pd was estimated at similar to 3.5 kcal mol(-1).
引用
收藏
页码：469 / 471
页数：3
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