Synthesis and Electrochemical Properties of Two-Dimensional Hafnium Carbide

被引:371
作者
Zhou, Jie [1 ,2 ]
Zha, Xianhu [1 ]
Zhou, Xiaobing [1 ]
Chen, Fanyan [1 ]
Gao, Guoliang [3 ]
Wang, Shuwei [3 ]
Shen, Cai [3 ]
Chen, Tao [1 ]
Zhi, Chunyi [4 ]
Eklund, Per [5 ]
Du, Shiyu [1 ]
Xue, Jianming [6 ,7 ]
Shi, Weiqun [8 ,9 ]
Chai, Zhifang [8 ,9 ]
Huang, Qing [1 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Engn & Technol, Engn Lab Specialty Fibers & Nucl Energy Mat, Ningbo 315201, Zhejiang, Peoples R China
[2] Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Ningbo Inst Mat Engn & Technol, Energy Storage Div, Ningbo 315201, Zhejiang, Peoples R China
[4] City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China
[5] Linkoping Univ, IFM, Thin Film Phys Div, S-58183 Linkoping, Sweden
[6] Peking Univ, CAPT, State Key Lab Nucl Phys & Technol, Beijing 100871, Peoples R China
[7] Peking Univ, IFSA Collaborat Innovat Ctr, MoE, Beijing 100871, Peoples R China
[8] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China
[9] Chinese Acad Sci, Inst High Energy Phys, Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
MXenes; selective etching; 2D materials; DFT calculations; electrochemical properties; TRANSITION-METAL CARBIDES; 2D TITANIUM CARBIDE; MECHANICAL-PROPERTIES; MOLYBDENUM CARBIDE; SURFACE-STRUCTURE; LAYERED CARBIDES; MXENE; NANOSHEETS; INTERCALATION; TI3C2;
D O I
10.1021/acsnano.7b00030
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate fabrication of a two-dimensional Hf-containing MXene, Hf3C2Tz, by selective etching of a layered parent Hf-3[Al(Si)](4)C-6 compound. A substitutional solution of Si on Al sites effectively weakened the interfacial adhesion between Hf-C and Al(Si)-C sublayers within the unit cell of the parent compound, facilitating the subsequent selective etching. The underlying mechanism of the Si-alloying-facilitated etching process is thoroughly studied by first-principles density functional calculations. The result showed that more valence electrons of Si than Al weaken the adhesive energy of the etching interface. The MXenes were determined to be flexible and conductive. Moreover, this 2D Hf-containing MXene material showed reversible volumetric capacities of 1567 and 504 mAh cm(-3) for lithium and sodium ions batteries, respectively, at a current density of 200 mAg(-1) after 200 cycles. Thus, Hf3C2Tz MXenes with a 2D structure are candidate anode materials for metal-ion intercalation, especially for applications where size matters.
引用
收藏
页码:3841 / 3850
页数:10
相关论文
共 60 条
  • [1] Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)
    Anasori, Babak
    Xie, Yu
    Beidaghi, Majid
    Lu, Jun
    Hosler, Brian C.
    Hultman, Lars
    Kent, Paul R. C.
    Gogotsi, Yury
    Barsoum, Michel W.
    [J]. ACS NANO, 2015, 9 (10) : 9507 - 9516
  • [2] The MN+1AXN phases:: A new class of solids;: Thermodynamically stable nanolaminates
    Barsoum, MW
    [J]. PROGRESS IN SOLID STATE CHEMISTRY, 2000, 28 (1-4) : 201 - 281
  • [3] Pseudocapacitive Electrodes Produced by Oxidant-Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene)
    Boota, Muhammad
    Anasori, Babak
    Voigt, Cooper
    Zhao, Meng-Qiang
    Barsoum, Michel W.
    Gogotsi, Yury
    [J]. ADVANCED MATERIALS, 2016, 28 (07) : 1517 - 1522
  • [4] Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
    Butler, Sheneve Z.
    Hollen, Shawna M.
    Cao, Linyou
    Cui, Yi
    Gupta, Jay A.
    Gutierrez, Humberto R.
    Heinz, Tony F.
    Hong, Seung Sae
    Huang, Jiaxing
    Ismach, Ariel F.
    Johnston-Halperin, Ezekiel
    Kuno, Masaru
    Plashnitsa, Vladimir V.
    Robinson, Richard D.
    Ruoff, Rodney S.
    Salahuddin, Sayeef
    Shan, Jie
    Shi, Li
    Spencer, Michael G.
    Terrones, Mauricio
    Windl, Wolfgang
    Goldberger, Joshua E.
    [J]. ACS NANO, 2013, 7 (04) : 2898 - 2926
  • [5] CO2 and temperature dual responsive "Smart'' MXene phases
    Chen, Jing
    Chen, Ke
    Tong, Dingyi
    Huang, Youju
    Zhang, Jiawei
    Xue, Jianming
    Huang, Qing
    Chen, Tao
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (02) : 314 - 317
  • [6] Ci L, 2010, NAT MATER, V9, P430, DOI [10.1038/nmat2711, 10.1038/NMAT2711]
  • [7] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
    Coleman, Jonathan N.
    Lotya, Mustafa
    O'Neill, Arlene
    Bergin, Shane D.
    King, Paul J.
    Khan, Umar
    Young, Karen
    Gaucher, Alexandre
    De, Sukanta
    Smith, Ronan J.
    Shvets, Igor V.
    Arora, Sunil K.
    Stanton, George
    Kim, Hye-Young
    Lee, Kangho
    Kim, Gyu Tae
    Duesberg, Georg S.
    Hallam, Toby
    Boland, John J.
    Wang, Jing Jing
    Donegan, John F.
    Grunlan, Jaime C.
    Moriarty, Gregory
    Shmeliov, Aleksey
    Nicholls, Rebecca J.
    Perkins, James M.
    Grieveson, Eleanor M.
    Theuwissen, Koenraad
    McComb, David W.
    Nellist, Peter D.
    Nicolosi, Valeria
    [J]. SCIENCE, 2011, 331 (6017) : 568 - 571
  • [8] Synthesis and characterization of two-dimensional Nb4C3 (MXene)
    Ghidiu, M.
    Naguib, M.
    Shi, C.
    Mashtalir, O.
    Pan, L. M.
    Zhang, B.
    Yang, J.
    Gogotsi, Y.
    Billinge, S. J. L.
    Barsoum, M. W.
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (67) : 9517 - 9520
  • [9] Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance
    Ghidiu, Michael
    Lukatskaya, Maria R.
    Zhao, Meng-Qiang
    Gogotsi, Yury
    Barsoum, Michel W.
    [J]. NATURE, 2014, 516 (7529) : 78 - U171
  • [10] True Performance Metrics in Electrochemical Energy Storage
    Gogotsi, Y.
    Simon, P.
    [J]. SCIENCE, 2011, 334 (6058) : 917 - 918