Zinc-nickel-cobalt ternary hydroxide nanoarrays for high-performance supercapacitors

The development of high-capacity, stable cycling, and high mass loading cathode materials for asymmetric supercapacitors has been the subject of intense exploration. In this work, a well-aligned zinc-nickel-cobalt ternary (oxy)hydroxide (Zn-Ni-Co TOH) nanostructure with a controlled morphology is used, for the first time, as a high-performance cathode material for supercapacitors. Our findings demonstrate that precursor Zn-Ni-Co TOH materials can deliver superior capacity and rate capability to the Zn-Ni-Co oxide. A high mass loading of 7 mg cm(-2) on a carbon cloth substrate is achieved, accompanied by substantially improved facile ionic and electronic transport due to the highly open well-defined nanoarray architecture. The growth mechanism of Zn-Ni-Co TOH was studied in depth by scanning electron microscopy analysis. The optimized Zn-Ni-Co TOH-130 nanowire array electrode delivered an outstanding areal capacitance of 2.14 F cm(-2) (or a specific capacitance of 305 F g(-1)) at 3 mA cm(-2) and an excellent rate capability. Moreover, the asymmetric supercapacitor assembled with our Zn-Ni-Co TOH-130 cathode exhibited a maximum volumetric energy density of 2.43 mW h cm(-3) at a volumetric power density of 6 mW cm(-3) and a long-term cycling stability (153% retention after 10000 cycles), which is superior to the majority of the state-of-the-art supercapacitors. This work paves the way for the construction of high-capacity cathode materials for widespread applications including next-generation wearable energy-storage devices.