Anion coordination and anion-templated assembly under halogen bonding control

被引:153
作者
Metrangolo, Pierangelo [1 ]
Pilati, Tullio [2 ]
Terraneo, Giancarlo [1 ]
Biella, Serena [1 ]
Resnati, Giuseppe [1 ,2 ]
机构
[1] Politecn Milan, DCMIC G Natta, NFM Lab, I-20131 Milan, Italy
[2] Univ Milan, ISTM CNR, I-20133 Milan, Italy
关键词
SCN-CIRCLE-MINUS; MULTICOMPONENT MOLECULAR CONDUCTORS; RADICAL-CATION SALTS; HALIDE ION SYNTHON; X-RAY STRUCTURES; CRYSTAL-STRUCTURES; PHYSICAL-PROPERTIES; CARBON TETRABROMIDE; AQUEOUS-SOLUTION; COMPLEXES;
D O I
10.1039/b821300c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This highlight discusses a selected set of halogen-bonded architectures reported in the literature wherein anions function as halogen bonding acceptors. Some of these architectures have been assembled purposefully, others have been obtained serendipitously. This paper is perhaps the first attempt to prove the effectiveness of halogen bonding in anion coordination and anion-templated assembly. A corollary of this attempt is that anions are particularly robust tectons in halogen bonding driven self-assembly processes. The focus here is particularly on halide anions and their ability to afford a wide variety of supramolecular architectures in a rational and predictable way. A brief inventory of other anions and their behaviour in self-assembly processes based on halogen bonding is also given.
引用
收藏
页码:1187 / 1196
页数:10
相关论文
共 169 条
[1]   ANTINEOPLASTIC AGENTS .27. SINGLE CRYSTAL X-RAY STRUCTURES OF CHEMOTHERAPEUTIC AGENTS .3. STRUCTURE OF 1,4-DIAZABICYCLO[2.2.1]HEPTANES, A NEW HETEROCYCLIC RING SYSTEM [J].
ABRAHAM, DJ ;
ROSENSTEIN, RD ;
PETTIT, GR .
JOURNAL OF MEDICINAL CHEMISTRY, 1971, 14 (11) :1141-+
[2]   EPR and DFT studies of the one-electron reduction product of phospholium cations [J].
Adkine, P ;
Cantat, T ;
Deschamps, E ;
Ricard, L ;
Mézailles, N ;
Le Floch, P ;
Geoffroy, M .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (07) :862-868
[3]   What anions do to N-H-containing receptors [J].
Amendola, Valeria ;
Esteban-Gomez, David ;
Fabbrizzi, Luigi ;
Licchelli, Maurizio .
ACCOUNTS OF CHEMICAL RESEARCH, 2006, 39 (05) :343-353
[4]   Preparation and conversion of N-halomethylpyridinium halides.: Comparison with related compounds [J].
Anders, E ;
Opitz, A ;
Wermann, K ;
Wiedel, B ;
Walther, M ;
Imhof, W ;
Görls, H .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (09) :3113-3121
[5]   N-confused calix[4]pyrroles [J].
Anzenbacher, Pavel, Jr. ;
Nishiyabu, Ryuhei ;
Palacios, Manuel A. .
COORDINATION CHEMISTRY REVIEWS, 2006, 250 (23-24) :2929-2938
[6]   Anionic amido N-heterocyclic carbenes: Synthesis of covalently tethered lanthanide-carbene complexes [J].
Arnold, PL ;
Mungur, SA ;
Blake, AJ ;
Wilson, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (48) :5981-5984
[7]   The nature of Halogen•••Halide synthons:: Theoretical and crystallographic studies [J].
Awwadi, Firas F. ;
Willett, Roger D. ;
Peterson, Kirk A. ;
Twamley, Brendan .
JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (12) :2319-2328
[8]   The aryl chlorine-halide ion synthon and its role in the control of the crystal structures of tetrahalocuprate(II) ions [J].
Awwadi, Firas F. ;
Willett, Roger D. ;
Twamley, Brendan .
CRYSTAL GROWTH & DESIGN, 2007, 7 (04) :624-632
[9]   The nature of halogen ... halogen synthons: Crystallographic and theoretical studies [J].
Awwadi, Firas F. ;
Willett, Roger D. ;
Peterson, Kirk A. ;
Twamley, Brendan .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (35) :8952-8960
[10]  
BAILEY RD, 2000, CRYST ENG, V0003