A chloro-bridged dinuclear phosphinitopalladium complex, di-μ-chloro-bis[(diphenoxyphos-phinite-κP)(diphenoxy-phosphinito-κP)palladium(II)]

被引：3

作者：

Gniewek, Andrzej ^{[1
]}

Pryjomska-Ray, Iweta ^{[1
]}

Trzeciak, Anna M. ^{[1
]}

Ziolkowski, Jozef J. ^{[1
]}

Lis, Tadeusz ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷

关键词：

D O I：

10.1107/S0108270106034500

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Pd-2(C12H10O3P)(2)Cl-2(C12H11O3P)(2)], consists of a dinuclear mu-chloro-bridged palladium unit with two diphenoxy-phosphinite groups per Pd atom, linked together by a hydrogen bond. The asymmetric unit contains one half of the mol-ecule, with the other half generated by an inversion centre. The geometry around the P atoms may be described as distorted tetra-hedral. Adjacent mol-ecules of the complex are linked by weak C-HcO and C-HcCl hydrogen bonds. The structure is additionally stabilized by pi-pi stacking inter-actions between the aryl rings. These inter-actions form a herring-bone pattern in the crystal structure.

引用

页码：M491 / M494

页数：4

共 21 条

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