A chloro-bridged dinuclear phosphinitopalladium complex, di-μ-chloro-bis[(diphenoxyphos-phinite-κP)(diphenoxy-phosphinito-κP)palladium(II)]

被引：3

作者：

Gniewek, Andrzej ^{[1
]}

Pryjomska-Ray, Iweta ^{[1
]}

Trzeciak, Anna M. ^{[1
]}

Ziolkowski, Jozef J. ^{[1
]}

Lis, Tadeusz ^{[1
]}

机构：

[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷

关键词：

D O I：

10.1107/S0108270106034500

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Pd-2(C12H10O3P)(2)Cl-2(C12H11O3P)(2)], consists of a dinuclear mu-chloro-bridged palladium unit with two diphenoxy-phosphinite groups per Pd atom, linked together by a hydrogen bond. The asymmetric unit contains one half of the mol-ecule, with the other half generated by an inversion centre. The geometry around the P atoms may be described as distorted tetra-hedral. Adjacent mol-ecules of the complex are linked by weak C-HcO and C-HcCl hydrogen bonds. The structure is additionally stabilized by pi-pi stacking inter-actions between the aryl rings. These inter-actions form a herring-bone pattern in the crystal structure.

引用

页码：M491 / M494

页数：4

共 17 条

[1] Di-μ-chloro-bis[chloro(tricyclohexylphosphine-κP)mercury(II)]
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[3] Inhibition of a palladium(II) catalyst upon formation of a di-μ-chloro complex:: di-μ-chloro-bis[1,2-bis(diphenylphosphino)ethane-P,P′]-dipalladium(II) bis(tetrafluoroborate) bis(deuterochloroform) solvate
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[4] Trans-di-μ-chloro-bis[chloro(trimethyl-phosphine-P) platinum(II)]
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Acta Crystallographica, Section C: Crystal Structure Communications, 1996, 52 (pt 8): : 1942 - 1943
[5] STRUCTURE AND MAGNETISM IN THE CHLORO-BRIDGED COPPER(II) COMPLEX DI-MU-CHLORO-BIS[CHLOROBIS(4-METHYLOXAZOLE)COPPER(II)]
MARSH, WE
EGGLESTON, DS
HATFIELD, WE
HODGSON, DJ
INORGANICA CHIMICA ACTA-ARTICLES, 1983, 70 (02): : 137 - 142
[6] The allyl complex di-μ-chloro-bis{[(1,2,3-η)-1-(ethoxycarbonyl)-5,5-dimethyl-4-oxohexenyl]palladium(II)}
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[7] Novel di-μ-chloro-bis[chloro(4,7-dimethyl-1,10-phenanthroline)cadmium(II)] dimer complex: synthesis, spectral, thermal, and crystal structure studies
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[8] Novel di-μ-chloro-bis[chloro(4,7-dimethyl-1,10-phenanthroline)cadmium(II)] dimer complex: synthesis, spectral, thermal, and crystal structure studies
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[10] X-ray single-crystal structure of a novel di-μ-chloro-bis[chloro(2,9-dimethyl-1,10-phenanthroline)nickel(II)] complex: synthesis, and spectral and thermal studies
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