Practical synthesis of an L-fructose-derived ketone catalyst for asymmetric epoxidation of olefins

被引：50
作者：
Zhao, Mei-Xin [1 ]
Shi, Yian [1 ]
机构：
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 14期
关键词：
D O I：
10.1021/jo060335k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An L-fructose-derived ketone catalyst for asymmetric epoxidation of trans- and trisubstituted olefins was efficiently prepared from L-sorbose in five steps.
引用
收藏
页码：5377 / 5379
页数：3
相关论文
共 50 条
  • [21] Organocatalytic oxidation: Development of ketone catalysts for asymmetric epoxidation of olefins with broad scope.
    Shi, Y
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U71 - U71
  • [22] Asymmetric Epoxidation of Olefins Catalyzed by Substituted Aminobenzimidazole Manganese Complexes Derived from L-Proline
    Tian, Jing
    Lin, Jin
    Zhang, Jisheng
    Xia, Chungu
    Sun, Wei
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (03) : 593 - 600
  • [23] Synthesis of Bulky Epoxides via Asymmetric Epoxidation of Bulky Olefins
    Sun Yun-Kai
    Yang Nian-Fa
    Wu Shi
    Ling Ying
    Ouyang Kun-Bing
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2009, 30 (08): : 1559 - 1565
  • [24] Asymmetric epoxidation by chiral ketones derived from carbocyclic analogues of fructose
    Wang, ZX
    Miller, SM
    Anderson, OP
    Shi, Y
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (02) : 521 - 530
  • [25] Studies on the synthesis of terpene-derived chiral ketone and iminium salt catalysts for asymmetric olefin epoxidation
    Overly, Kenneth
    Williams, Christine
    Bouchard, Jocelyn
    Trainor, Alison
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [26] Biomimetic catalyst: Salen-metal complex catalyzed asymmetric epoxidation of the olefins
    Zhou, ZM
    Li, LY
    Xu, Q
    Yu, CX
    [J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (04) : 347 - 354
  • [27] A practical and simple method of recycling catalyst in asymmetric aminohydroxylation of Olefins
    Sun, Xiao Li
    Jin, Ying
    He, Wei
    Nan, Peng Juan
    Zhang, Sheng Yong
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2007, 28 (08) : 1422 - 1424
  • [28] Synthesis of (+)-Ambrisentan via Chiral Ketone-Catalyzed Asymmetric Epoxidation
    Peng, Xianyou
    Li, Peijun
    Shi, Yian
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (01) : 701 - 703
  • [29] Organocatalytic asymmetric epoxidation of olefins catalyzed by chiral ketones derived from carbohydrates
    Wang Chun
    Gao Yongjun
    Zhang Yingqun
    Wang Zhi
    Ma Jingjun
    [J]. PROGRESS IN CHEMISTRY, 2006, 18 (06) : 761 - 767
  • [30] Design and synthesis of chiral ketones for catalytic asymmetric epoxidation of unfunctionalized olefins
    [J]. J Am Chem Soc, 24 (5943-5952):
12345