PREDICTION OF LIQUID-LIQUID EQUILIBRIA FOR POLYETHYLENE GLYCOL BASED AQUEOUS TWO-PHASE SYSTEM BY ASOG AND UNIFAC METHOD

被引：8
|
作者：
Perumalsamy, M. [1 ]
Murugesan, T. [2 ]
机构：
[1] Natl Inst Technol, Dept Chem Engn, Tiruchirappalli 620015, India
[2] Univ Teknol PETRONAS, Chem Engn Programme, Tronoh 31750, Perak, Malaysia
来源：
BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING | 2009年 / 26卷 / 01期
关键词：
Liquid-Liquid equilibria; Polyethylene glycol; Sodium citrate; ASOG; UNIFAC; PHASE-EQUILIBRIA; SODIUM-CITRATE; THERMODYNAMICS; SEPARATION; EXTRACTION; BEHAVIOR; SALTS; WATER;
D O I：
10.1590/S0104-66322009000100016
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Liquid-Liquid equilibrium data were obtained for the polyethylene glycol(2000)(PEG(2000))-sodium citrate-water system at 298.15, 308.15 and 318.15 K. The effect of temperature on binodal and tie line data was studied and published in a previous article (Murugesan and Perumalsamy, 2005). The interaction parameters of ASOG and UNIFAC models were estimated using the LLE data of PEG(2000)-sodium citrate-water system and are used to predict the LLE data for PEG(6000)-sodium citrate-water system at 298.15, 308.15 and 318.15 K (literature data). The predicted LLE data by both ASOG and UNIFAC models showed good agreement with the experimental and literature data.
引用
收藏
页码：171 / 180
页数：10
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